Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K

Robin J. Blagg; Christopher A. Muryn; Eric J L McInnes; Floriana Tuna; Richard E P Winpenny

doi:10.1002/anie.201101932

Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K

Robin J. Blagg, Christopher A. Muryn, Eric J L McInnes, Floriana Tuna, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Single-molecule magnets: A square-pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures as high as 40 K. The thermal energy barrier to relaxation of magnetization of this single-molecule magnet is 530 K and is the largest yet observed for any d- or f-block cluster compound. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	6530-6533
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	29
DOIs	https://doi.org/10.1002/anie.201101932
Publication status	Published - 11 Jul 2011

Keywords

cluster compounds
dysprosium
lanthanides
magnetic properties
single-molecule magnets

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10.1002/anie.201101932

CCDC 817819: Experimental Crystal Structure Determination
Blagg, R. J. (Contributor), Muryn, C. A. (Contributor), Mcinnes, E. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccwg08l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwg08l&sid=DataCite
Dataset

Cite this

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title = "Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K",

abstract = "Single-molecule magnets: A square-pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures as high as 40 K. The thermal energy barrier to relaxation of magnetization of this single-molecule magnet is 530 K and is the largest yet observed for any d- or f-block cluster compound. Copyright {\textcopyright} 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "cluster compounds, dysprosium, lanthanides, magnetic properties, single-molecule magnets",

author = "Blagg, {Robin J.} and Muryn, {Christopher A.} and McInnes, {Eric J L} and Floriana Tuna and Winpenny, {Richard E P}",

year = "2011",

month = jul,

day = "11",

doi = "10.1002/anie.201101932",

language = "English",

volume = "50",

pages = "6530--6533",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K

AU - Blagg, Robin J.

AU - Muryn, Christopher A.

AU - McInnes, Eric J L

AU - Tuna, Floriana

AU - Winpenny, Richard E P

PY - 2011/7/11

Y1 - 2011/7/11

N2 - Single-molecule magnets: A square-pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures as high as 40 K. The thermal energy barrier to relaxation of magnetization of this single-molecule magnet is 530 K and is the largest yet observed for any d- or f-block cluster compound. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Single-molecule magnets: A square-pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures as high as 40 K. The thermal energy barrier to relaxation of magnetization of this single-molecule magnet is 530 K and is the largest yet observed for any d- or f-block cluster compound. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - cluster compounds

KW - dysprosium

KW - lanthanides

KW - magnetic properties

KW - single-molecule magnets

U2 - 10.1002/anie.201101932

DO - 10.1002/anie.201101932

M3 - Article

SN - 1433-7851

VL - 50

SP - 6530

EP - 6533

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Single pyramid magnets: Dy5 pyramids with slow magnetic relaxation to 40 K

Abstract

Keywords

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Datasets

CCDC 817819: Experimental Crystal Structure Determination

Cite this