Single-scan Ultra-selective 1D Total Correlation Spectroscopy

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Selective 1D TOCSY is a powerful tool in the assignment of NMR spectra of organic molecules. Here an order of magnitude improvement in selectivity, allowing overlapping multiplets to be excited separately, is achieved in a single scan using the very recent GEMSTONE method. The new experiment is illustrated using an antibiotic and a mixture of diastereomers.

Original languageEnglish
Pages (from-to)2368-2371
Number of pages4
JournalChemical Communications
Issue number19
Publication statusPublished - 7 Mar 2021


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