@article{2896b4760b8344f28531c2a514673c0f,
title = "Size selective and volume exclusion effects on ion transfer at the silicalite modified liquid-liquid interface",
abstract = "The modification of the liquid/liquid interface with membranes of silicalite, a neutral framework zeolite, is used to extend the potential window. This feature allows the observation of the transfer of extremely hydrophilic ions, due to the size-exclusion of organic ions from the interior of the zeolitic framework. Similarly, volume exclusion effects are shown to affect facilitated ion transfer processes involving alkali metal cations. In contrast, proton transfer is largely unaffected by the presence of the zeolite, which is suggestive of more rapid diffusion processes within the interior of the framework. The technique of liquid/liquid electrochemistry should allow the measurement of solution phase transport parameters for ions within microporous hosts. {\textcopyright} 2005 American Chemical Society.",
keywords = "Cation exchange, Liquid-liquid interface (size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface), Silicalites Role: NUU (Other use, unclassified), PEP (Physical, engineering or chemical process), PYP (Physical process), PROC (Process), USES (Uses) (size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface), Size effect, Volume (vol. effect, size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface), size vol selective ion transfer silicalite liq liq interface",
author = "Stephenson, {Michael J.} and King, {Andrew J.} and Holmes, {Stuart M.} and Dryfe, {Robert A W}",
note = "CAN 143:466882 66-4 Surface Chemistry and Colloids Journal 1520-6106 written in English. 107-06-2 (1,2-Dichloroethane); 7732-18-5 (Water) Role: NUU (Other use, unclassified), USES (Uses) (liq.; size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface); 7439-93-2 (Lithium) Role: PEP (Physical, engineering or chemical process), PYP (Physical process), PROC (Process) (lithium (I) ion; size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface); 7440-09-7 (Potassium) Role: PEP (Physical, engineering or chemical process), PYP (Physical process), PROC (Process) (potassium (I) ion; size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface); 12408-02-5 (Hydrogen ion) Role: PEP (Physical, engineering or chemical process), PYP (Physical process), PROC (Process) (size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface); 7440-23-5 (Sodium) Role: PEP (Physical, engineering or chemical process), PYP (Physical process), PROC (Process) (sodium (I) ion; size selective and vol. exclusion effects on ion transfer at silicalite modified liq.-liq. interface)",
year = "2005",
month = oct,
day = "20",
doi = "10.1021/jp051774a",
language = "English",
volume = "109",
pages = "19377--19384",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "41",
}