Sky radiance at a coastline and effects of land and ocean reflectivities

We present a unique case study of the spectral sky radiance distribution above a coastline. Results are shown from a measurement campaign in Italy involving three diode array spectroradiometers which are compared to 3-D model simulations from the Monte Carlo model MYSTIC. On the coast, the surrounding is split into two regions, a diffusely reflecting land surface and a water surface which features a highly anisotropic reflectance function. The reflectivities and hence the resulting radiances are a nontrivial function of solar zenith and azimuth angle and wavelength. We show that for low solar zenith angles (SZAs) around noon, the higher land albedo causes the sky radiance at 20° above the horizon to increase by 50ĝ€% in the near infrared at 850ĝ€nm for viewing directions towards the land with respect to the ocean. Comparing morning and afternoon radiances highlights the effect of the ocean's sun glint at high SZA, which contributes around 10ĝ€% to the measured radiance ratios. The model simulations generally agree with the measurements to better than 10ĝ€%. We investigate the individual effects of model input parameters representing land and ocean albedo and aerosols. Different land and ocean bi-directional reflectance functions (BRDFs) do not generally improve the model agreement. However, consideration of the uncertainties in the diurnal variation of aerosol optical depth can explain the remaining discrepancies between measurements and model. We further investigate the anisotropy effect of the ocean BRDF which is featured in the zenith radiances. Again, the uncertainty of the aerosol loading is dominant and obscures the modelled sun glint effect of 7ĝ€% at 650ĝ€nm. Finally, we show that the effect on the zenith radiance is restricted to a few kilometres from the coastline by model simulations along a perpendicular transect and by comparing the radiances at the coast to those measured at a site 15ĝ€km inland. Our findings are relevant to, for example, ground-based remote sensing of aerosol characteristics, since a common technique is based on sky radiance measurements along the solar almucantar.