TY - JOUR
T1 - Slow Magnetic Relaxation in Distorted Tetrahedral Dy(III) Aryloxide Complexes
AU - Parmar, Vijay
AU - Gransbury, Gemma Kate
AU - Whitehead, George F. S.
AU - Mills, David P
AU - Winpenny, Richard E. P.
N1 - Funding Information:
We thank the University of Manchester for the President’s Doctoral Scholarship for V. P. and access to the Computational Shared Facility, the European Research Council (ADG-786734 for R. E. P. W. and CoG-816268 for D. P. M. and G. K. G.) and the UK EPSRC (EP/P002560/1, EP/R011079/1) for funding, and the EPSRC National Electron Paramagnetic Resonance Service for access to the SQUID magnetometer (EP/S033181/1). Research data files supporting this publication are available from Figshare at DOI: 10.48420/14635464.
Publisher Copyright:
© The Royal Society of Chemistry 2021.
PY - 2021/9/18
Y1 - 2021/9/18
N2 - Three distorted tetrahedral Dy(iii) aryloxide complexes, [Na(THF)
6][Dy(OAr
Ad2tBu)
2Cl
2] (1) (OAr
Ad2tBu= OC
6H
2Adamantyl
2-2,6-
tBu-4) and [Na(THF)
6][Dy(OMes*)
3X] (X = Cl, 2; BH
4, 3), (OMes* = OC
6H
2
tBu
3-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic relaxation at zero field, with relaxation rates 1 < 2 < 3.
AB - Three distorted tetrahedral Dy(iii) aryloxide complexes, [Na(THF)
6][Dy(OAr
Ad2tBu)
2Cl
2] (1) (OAr
Ad2tBu= OC
6H
2Adamantyl
2-2,6-
tBu-4) and [Na(THF)
6][Dy(OMes*)
3X] (X = Cl, 2; BH
4, 3), (OMes* = OC
6H
2
tBu
3-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic relaxation at zero field, with relaxation rates 1 < 2 < 3.
U2 - 10.1039/D1CC02707G
DO - 10.1039/D1CC02707G
M3 - Article
C2 - 34519290
SN - 1359-7345
VL - 57
SP - 9208
EP - 9211
JO - Chemical Communications
JF - Chemical Communications
IS - 73
ER -