Solution crystallisation via a submerged liquid-liquid phase boundary: Oiling out

P. E. Bonnett; K. J. Carpenter; S. Dawson; R. J. Davey

doi:10.1039/b212062c

Solution crystallisation via a submerged liquid-liquid phase boundary: Oiling out

P. E. Bonnett, K. J. Carpenter, S. Dawson, R. J. Davey

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Abstract

In many situations the process of crystallisation from solution is known to occur via metastable crystalline states (polymorphs or solvates). Here we present what we believe to be a novel example of small molecule crystallisation in which the initial separation of a solute rich liquid phase precedes the crystallisation event. We believe this occurs because a submerged liquid-liquid phase boundary is accessible within the metastable zone of the crystal nucleation process.

Original language	English
Pages (from-to)	698-699
Number of pages	1
Journal	Chemical Communications
Volume	9
Issue number	6
DOIs	https://doi.org/10.1039/b212062c
Publication status	Published - 21 Mar 2003

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title = "Solution crystallisation via a submerged liquid-liquid phase boundary: Oiling out",

abstract = "In many situations the process of crystallisation from solution is known to occur via metastable crystalline states (polymorphs or solvates). Here we present what we believe to be a novel example of small molecule crystallisation in which the initial separation of a solute rich liquid phase precedes the crystallisation event. We believe this occurs because a submerged liquid-liquid phase boundary is accessible within the metastable zone of the crystal nucleation process.",

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AU - Bonnett, P. E.

AU - Carpenter, K. J.

AU - Dawson, S.

AU - Davey, R. J.

PY - 2003/3/21

Y1 - 2003/3/21

N2 - In many situations the process of crystallisation from solution is known to occur via metastable crystalline states (polymorphs or solvates). Here we present what we believe to be a novel example of small molecule crystallisation in which the initial separation of a solute rich liquid phase precedes the crystallisation event. We believe this occurs because a submerged liquid-liquid phase boundary is accessible within the metastable zone of the crystal nucleation process.

AB - In many situations the process of crystallisation from solution is known to occur via metastable crystalline states (polymorphs or solvates). Here we present what we believe to be a novel example of small molecule crystallisation in which the initial separation of a solute rich liquid phase precedes the crystallisation event. We believe this occurs because a submerged liquid-liquid phase boundary is accessible within the metastable zone of the crystal nucleation process.

UR - https://www.scopus.com/pages/publications/0037459494

U2 - 10.1039/b212062c

DO - 10.1039/b212062c

M3 - Article

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VL - 9

SP - 698

EP - 699

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Solution crystallisation via a submerged liquid-liquid phase boundary: Oiling out

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