Solvent hydrolysis and templating effects in the synthesis of metal-organic frameworks

Andrew D. Burrows, Kevin Cassar, Richard M W Friend, Mary F. Mahon, Sean P. Rigby, John E. Warren

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Hydrolysis of the DMF or DEF solvent influences the nature of the product observed in the reaction between zinc(II) nitrate and 1,4-benzenedicarboxylic acid, with dialkylammonium cations able to template the formation of anionic networks. © The Royal Society of Chemistry 2005.
    Original languageEnglish
    Pages (from-to)548-550
    Number of pages2
    JournalCrystEngComm
    Volume7
    DOIs
    Publication statusPublished - 12 Aug 2005

    Keywords

    • BUILDING
    • CARBOXYLATES
    • COORDINATION
    • COORDINATION} {POLYMERS
    • DESIGN
    • {DESIGN
    • SORPTION
    • METHANE
    • METHANE} {STORAGE
    • {POLYMERS
    • SECONDARY
    • SECONDARY} {BUILDING} {UNITS
    • {SECONDARY} {BUILDING} {UNITS
    • COORDINATION POLYMERS
    • METHANE STORAGE
    • {SORPTION
    • {STORAGE
    • {UNITS

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