Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

David S. Wragg; Grace M. Fullerton; Peter J. Byrne; Alexandra M Z Slawin; John E. Warren; Simon J. Teat; Russell E. Morris

doi:10.1039/c0dt01788d

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

David S. Wragg, Grace M. Fullerton, Peter J. Byrne, Alexandra M Z Slawin, John E. Warren, Simon J. Teat, Russell E. Morris

Science & Technology Facilities Council (STFC)

Research output: Contribution to journal › Article › peer-review

Abstract

We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	4926-4932
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	18
DOIs	https://doi.org/10.1039/c0dt01788d
Publication status	Published - 14 May 2011
Externally published	Yes

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10.1039/c0dt01788d

CCDC 683429: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Fullerton, G. M. (Contributor), Byrne, P. J. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Teat, S. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccqy53x, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqy53x&sid=DataCite
Dataset
CCDC 805445: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Fullerton, G. M. (Contributor), Byrne, P. J. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Teat, S. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw1434, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw1434&sid=DataCite
Dataset
CCDC 709229: Experimental Crystal Structure Determination
Wragg, D. S. (Contributor), Fullerton, G. M. (Contributor), Byrne, P. J. (Contributor), Slawin, A. M. Z. (Contributor), Warren, J. (Contributor), Teat, S. J. (Contributor) & Morris, R. E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccrt0cx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrt0cx&sid=DataCite
Dataset

Cite this

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title = "Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors",

abstract = "We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Wragg, {David S.} and Fullerton, {Grace M.} and Byrne, {Peter J.} and Slawin, {Alexandra M Z} and Warren, {John E.} and Teat, {Simon J.} and Morris, {Russell E.}",

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T1 - Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

AU - Wragg, David S.

AU - Fullerton, Grace M.

AU - Byrne, Peter J.

AU - Slawin, Alexandra M Z

AU - Warren, John E.

AU - Teat, Simon J.

AU - Morris, Russell E.

N1 - 18

PY - 2011/5/14

Y1 - 2011/5/14

N2 - We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. © 2011 The Royal Society of Chemistry.

AB - We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c0dt01788d

DO - 10.1039/c0dt01788d

M3 - Article

SN - 1477-9234

VL - 40

SP - 4926

EP - 4932

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

Abstract

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Datasets

CCDC 683429: Experimental Crystal Structure Determination

CCDC 805445: Experimental Crystal Structure Determination

CCDC 709229: Experimental Crystal Structure Determination

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