Solvothermal synthesis of a tetradecametallic FeIII cluster

David M. Low; Leigh F. Jones; Aidan Bell; Euan K. Brechin; Talal Mallah; Eric Rivière; Simon J. Teat; Eric J L McInnes

doi:10.1002/anie.200351865

Solvothermal synthesis of a tetradecametallic FeIII cluster

David M. Low, Leigh F. Jones, Aidan Bell, Euan K. Brechin, Talal Mallah, Eric Rivière, Simon J. Teat, Eric J L McInnes

Research output: Contribution to journal › Article › peer-review

Abstract

Solvothermal techniques allow the crystallization of high nuclearity products that are otherwise inaccessible by conventional techniques, directly from the reaction mixture. By this method, the reaction of the triangular species [Fe3O(OAc)6-(H2O)3] CI with benzotriazole (BtaH) produces an [Fe14] cluster (depicted) with a very large spin ground state.

Original language	English
Pages (from-to)	3781-3784
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	32
DOIs	https://doi.org/10.1002/anie.200351865
Publication status	Published - 18 Aug 2003

Keywords

Cluster compounds
Iron
Magnetic properties
N ligands
Solvothermal chemistry

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10.1002/anie.200351865

http://www3.interscience.wiley.com/cgi-bin/abstract/104553643/

CCDC 209766: Experimental Crystal Structure Determination
Low, D. M. (Contributor), Jones, L. F. (Contributor), Bell, A. (Contributor), Brechin, E. K. (Contributor), Mallah, T. (Contributor), Rivière, E. (Contributor), Teat, S. J. (Contributor) & Mcinnes, E. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2004
DOI: 10.5517/cc718n5, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc718n5&sid=DataCite
Dataset

Cite this

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title = "Solvothermal synthesis of a tetradecametallic FeIII cluster",

abstract = "Solvothermal techniques allow the crystallization of high nuclearity products that are otherwise inaccessible by conventional techniques, directly from the reaction mixture. By this method, the reaction of the triangular species [Fe3O(OAc)6-(H2O)3] CI with benzotriazole (BtaH) produces an [Fe14] cluster (depicted) with a very large spin ground state.",

keywords = "Cluster compounds, Iron, Magnetic properties, N ligands, Solvothermal chemistry",

author = "Low, {David M.} and Jones, {Leigh F.} and Aidan Bell and Brechin, {Euan K.} and Talal Mallah and Eric Rivi{\`e}re and Teat, {Simon J.} and McInnes, {Eric J L}",

year = "2003",

month = aug,

day = "18",

doi = "10.1002/anie.200351865",

language = "English",

volume = "42",

pages = "3781--3784",

journal = "Angewandte Chemie - International Edition",

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T1 - Solvothermal synthesis of a tetradecametallic FeIII cluster

AU - Low, David M.

AU - Jones, Leigh F.

AU - Bell, Aidan

AU - Brechin, Euan K.

AU - Mallah, Talal

AU - Rivière, Eric

AU - Teat, Simon J.

AU - McInnes, Eric J L

PY - 2003/8/18

Y1 - 2003/8/18

N2 - Solvothermal techniques allow the crystallization of high nuclearity products that are otherwise inaccessible by conventional techniques, directly from the reaction mixture. By this method, the reaction of the triangular species [Fe3O(OAc)6-(H2O)3] CI with benzotriazole (BtaH) produces an [Fe14] cluster (depicted) with a very large spin ground state.

AB - Solvothermal techniques allow the crystallization of high nuclearity products that are otherwise inaccessible by conventional techniques, directly from the reaction mixture. By this method, the reaction of the triangular species [Fe3O(OAc)6-(H2O)3] CI with benzotriazole (BtaH) produces an [Fe14] cluster (depicted) with a very large spin ground state.

KW - Cluster compounds

KW - Iron

KW - Magnetic properties

KW - N ligands

KW - Solvothermal chemistry

U2 - 10.1002/anie.200351865

DO - 10.1002/anie.200351865

M3 - Article

SN - 1433-7851

VL - 42

SP - 3781

EP - 3784

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

Solvothermal synthesis of a tetradecametallic FeIII cluster

Abstract

Keywords

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Datasets

CCDC 209766: Experimental Crystal Structure Determination

Cite this