Abstract
Manganocene reacts with LiE(SiMe 3) 2 (E = P or As) to give [(η 5-Cp)Mn{μ-E(SiMe 3) 2}] 2, where E = P (1) or As (2). The temperature dependence of the magnetic susceptibility in 1 and 2 is due to antiferromagnetic exchange and to spin-crossover (SCO). Compound 2 shows two-step SCO with hysteresis, involving high-spin (S = 5/2) and intermediate-spin S = (3/2) Mn(ii). © 2012 The Royal Society of Chemistry.
| Original language | English |
|---|---|
| Pages (from-to) | 8087-8089 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Volume | 48 |
| Issue number | 65 |
| DOIs | |
| Publication status | Published - 21 Aug 2012 |
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CCDC 863320: Experimental Crystal Structure Determination
Scheuermayer, S. (Contributor), Tuna, F. (Contributor), Bodensteiner, M. (Contributor), Scheer, M. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxzc18, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxzc18&sid=DataCite
Dataset
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CCDC 863319: Experimental Crystal Structure Determination
Scheuermayer, S. (Contributor), Tuna, F. (Contributor), Bodensteiner, M. (Contributor), Scheer, M. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxzc07, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxzc07&sid=DataCite
Dataset