Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid)

Vitaliy Khutoryanskiy; Grigoriy A. Mun; Vitaliy V. Khutoryanskiy; Zauresh S. Nurkeeva; Perizat I. Urkimbaeva; Daulet Zhunuspaev

doi:10.1002/polb.20138

Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid)

Vitaliy Khutoryanskiy, Grigoriy A. Mun, Vitaliy V. Khutoryanskiy, Zauresh S. Nurkeeva, Perizat I. Urkimbaeva, Daulet Zhunuspaev

Research output: Contribution to journal › Article › peer-review

Abstract

Amphiphilic random copolymers based on vinyl ether of ethylene glycol and vinyl butyl ether as well as their polycomplexes with poly(acrylic acid) were studied as polymeric reagents for the stabilization of water/n-hexane emulsions. The emulsion stability strongly depended on the content of vinyl butyl ether in the copolymers as well as their concentration in solution. The more hydrophobic copolymers stabilized emulsions more efficiently. An increase in the temperature and the addition of inorganic salts reduced the emulsion lifetime. The formation of interpolymer complexes between the copolymers and poly(acrylic acid) significantly influenced the stability of the emulsions. © 2004 Wiley Periodicals, Inc.

Original language	English
Pages (from-to)	2625-2632
Number of pages	7
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	42
Issue number	14
DOIs	https://doi.org/10.1002/polb.20138
Publication status	Published - 15 Jul 2004

Keywords

Amphiphilic copolymers
Colloids
Emulsions
Interpolymer complexes
Stimuli-sensitive polymers
Surface activity
Vinyl ethers
Water-soluble polymers

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10.1002/polb.20138

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title = "Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid)",

abstract = "Amphiphilic random copolymers based on vinyl ether of ethylene glycol and vinyl butyl ether as well as their polycomplexes with poly(acrylic acid) were studied as polymeric reagents for the stabilization of water/n-hexane emulsions. The emulsion stability strongly depended on the content of vinyl butyl ether in the copolymers as well as their concentration in solution. The more hydrophobic copolymers stabilized emulsions more efficiently. An increase in the temperature and the addition of inorganic salts reduced the emulsion lifetime. The formation of interpolymer complexes between the copolymers and poly(acrylic acid) significantly influenced the stability of the emulsions. {\textcopyright} 2004 Wiley Periodicals, Inc.",

keywords = "Amphiphilic copolymers, Colloids, Emulsions, Interpolymer complexes, Stimuli-sensitive polymers, Surface activity, Vinyl ethers, Water-soluble polymers",

author = "Vitaliy Khutoryanskiy and Mun, {Grigoriy A.} and Khutoryanskiy, {Vitaliy V.} and Nurkeeva, {Zauresh S.} and Urkimbaeva, {Perizat I.} and Daulet Zhunuspaev",

year = "2004",

month = jul,

day = "15",

doi = "10.1002/polb.20138",

language = "English",

volume = "42",

pages = "2625--2632",

journal = "Journal of Polymer Science, Part B: Polymer Physics",

issn = "0887-6266",

publisher = "John Wiley & Sons Ltd",

number = "14",

}

Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid). / Khutoryanskiy, Vitaliy; Mun, Grigoriy A.; Khutoryanskiy, Vitaliy V. et al.
In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 42, No. 14, 15.07.2004, p. 2625-2632.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid)

AU - Khutoryanskiy, Vitaliy

AU - Mun, Grigoriy A.

AU - Khutoryanskiy, Vitaliy V.

AU - Nurkeeva, Zauresh S.

AU - Urkimbaeva, Perizat I.

AU - Zhunuspaev, Daulet

PY - 2004/7/15

Y1 - 2004/7/15

N2 - Amphiphilic random copolymers based on vinyl ether of ethylene glycol and vinyl butyl ether as well as their polycomplexes with poly(acrylic acid) were studied as polymeric reagents for the stabilization of water/n-hexane emulsions. The emulsion stability strongly depended on the content of vinyl butyl ether in the copolymers as well as their concentration in solution. The more hydrophobic copolymers stabilized emulsions more efficiently. An increase in the temperature and the addition of inorganic salts reduced the emulsion lifetime. The formation of interpolymer complexes between the copolymers and poly(acrylic acid) significantly influenced the stability of the emulsions. © 2004 Wiley Periodicals, Inc.

AB - Amphiphilic random copolymers based on vinyl ether of ethylene glycol and vinyl butyl ether as well as their polycomplexes with poly(acrylic acid) were studied as polymeric reagents for the stabilization of water/n-hexane emulsions. The emulsion stability strongly depended on the content of vinyl butyl ether in the copolymers as well as their concentration in solution. The more hydrophobic copolymers stabilized emulsions more efficiently. An increase in the temperature and the addition of inorganic salts reduced the emulsion lifetime. The formation of interpolymer complexes between the copolymers and poly(acrylic acid) significantly influenced the stability of the emulsions. © 2004 Wiley Periodicals, Inc.

KW - Amphiphilic copolymers

KW - Colloids

KW - Emulsions

KW - Interpolymer complexes

KW - Stimuli-sensitive polymers

KW - Surface activity

KW - Vinyl ethers

KW - Water-soluble polymers

U2 - 10.1002/polb.20138

DO - 10.1002/polb.20138

M3 - Article

SN - 0887-6266

VL - 42

SP - 2625

EP - 2632

JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

IS - 14

ER -

Stabilization of water/n-hexane emulsions by amphiphilic copolymers based on vinyl ethers and their polycomplexes with poly(acrylic acid)

Abstract

Keywords

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