Stable and Easily Handled Fe-III Catalysts for Hydrosilylation of Ketones and Aldehydes

Kailong Zhu; Michael P. Shaver; Stephen P. Thomas

doi:10.1002/ejoc.201500090

Stable and Easily Handled Fe-III Catalysts for Hydrosilylation of Ketones and Aldehydes

Kailong Zhu, Michael P. Shaver, Stephen P. Thomas

Planning, Property and Environmental Management

Research output: Contribution to journal › Article › peer-review

Abstract

The amine-bis(phenolate) iron(III)-catalysed reduction of ketones and aldehydes to the corresponding secondary and primary alcohols by a consecutive hydrosilylation/hydrolysis process is reported. The amine-bis(phenolate) iron(III) catalyst is easily accessible, stable towards moisture and air and has a broad substrate scope.

Original language	English
Pages (from-to)	2119-2123
Number of pages	5
Journal	European Journal of Organic Chemistry
Volume	2015
Issue number	10
DOIs	https://doi.org/10.1002/ejoc.201500090
Publication status	Published - Apr 2015

Keywords

Iron
Reduction
Hydrosilylation
Carbonyl compounds
Synthetic methods
ASYMMETRIC TRANSFER HYDROGENATION
ENANTIOSELECTIVE HYDROSILYLATION
RUTHENIUM COMPLEXES
CARBONYL-COMPOUNDS
AROMATIC KETONES
DIALKYL KETONES
IRON CATALYSTS
ALKYL
REDUCTION
MECHANISM

Access to Document

10.1002/ejoc.201500090

Cite this

@article{053049f44747437283762cc2de0bd2aa,

title = "Stable and Easily Handled Fe-III Catalysts for Hydrosilylation of Ketones and Aldehydes",

abstract = "The amine-bis(phenolate) iron(III)-catalysed reduction of ketones and aldehydes to the corresponding secondary and primary alcohols by a consecutive hydrosilylation/hydrolysis process is reported. The amine-bis(phenolate) iron(III) catalyst is easily accessible, stable towards moisture and air and has a broad substrate scope.",

keywords = "Iron, Reduction, Hydrosilylation, Carbonyl compounds, Synthetic methods, ASYMMETRIC TRANSFER HYDROGENATION, ENANTIOSELECTIVE HYDROSILYLATION, RUTHENIUM COMPLEXES, CARBONYL-COMPOUNDS, AROMATIC KETONES, DIALKYL KETONES, IRON CATALYSTS, ALKYL, REDUCTION, MECHANISM",

author = "Kailong Zhu and Shaver, {Michael P.} and Thomas, {Stephen P.}",

year = "2015",

month = apr,

doi = "10.1002/ejoc.201500090",

language = "English",

volume = "2015",

pages = "2119--2123",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "John Wiley & Sons Ltd",

number = "10",

}

TY - JOUR

T1 - Stable and Easily Handled Fe-III Catalysts for Hydrosilylation of Ketones and Aldehydes

AU - Zhu, Kailong

AU - Shaver, Michael P.

AU - Thomas, Stephen P.

PY - 2015/4

Y1 - 2015/4

N2 - The amine-bis(phenolate) iron(III)-catalysed reduction of ketones and aldehydes to the corresponding secondary and primary alcohols by a consecutive hydrosilylation/hydrolysis process is reported. The amine-bis(phenolate) iron(III) catalyst is easily accessible, stable towards moisture and air and has a broad substrate scope.

AB - The amine-bis(phenolate) iron(III)-catalysed reduction of ketones and aldehydes to the corresponding secondary and primary alcohols by a consecutive hydrosilylation/hydrolysis process is reported. The amine-bis(phenolate) iron(III) catalyst is easily accessible, stable towards moisture and air and has a broad substrate scope.

KW - Iron

KW - Reduction

KW - Hydrosilylation

KW - Carbonyl compounds

KW - Synthetic methods

KW - ASYMMETRIC TRANSFER HYDROGENATION

KW - ENANTIOSELECTIVE HYDROSILYLATION

KW - RUTHENIUM COMPLEXES

KW - CARBONYL-COMPOUNDS

KW - AROMATIC KETONES

KW - DIALKYL KETONES

KW - IRON CATALYSTS

KW - ALKYL

KW - REDUCTION

KW - MECHANISM

U2 - 10.1002/ejoc.201500090

DO - 10.1002/ejoc.201500090

M3 - Article

SN - 1434-193X

VL - 2015

SP - 2119

EP - 2123

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 10

ER -

Stable and Easily Handled Fe-III Catalysts for Hydrosilylation of Ketones and Aldehydes

Abstract

Keywords

Access to Document

Fingerprint

Cite this