Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

Jamespandi Annaraj; Jaeheung Cho; Yong Min Lee; Sung Yeon Kim; Reza Latifi; Sam P. De Visser; Wonwoo Nam

doi:10.1002/anie.200900118

Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

Jamespandi Annaraj, Jaeheung Cho, Yong Min Lee, Sung Yeon Kim, Reza Latifi, Sam P. De Visser, Wonwoo Nam

Research output: Contribution to journal › Article › peer-review

Abstract

The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	4150-4153
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	23
DOIs	https://doi.org/10.1002/anie.200900118
Publication status	Published - 25 May 2009

Keywords

Axial ligand effects
Bioinorganic chemistry
Enzyme models
Manganese
Nucleophilic reactions

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10.1002/anie.200900118

http://www3.interscience.wiley.com/cgi-bin/fulltext/122377084/PDFSTART

CCDC 715699: Experimental Crystal Structure Determination
Annaraj, J. (Contributor), Cho, J. (Contributor), Lee, Y. M. (Contributor), Kim, S. Y. (Contributor), Latifi, R. (Contributor), De Visser, S. (Contributor) & Nam, W. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccs0r2l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccs0r2l&sid=DataCite
Dataset

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title = "Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex",

abstract = "The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. {\textcopyright} 2009 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Axial ligand effects, Bioinorganic chemistry, Enzyme models, Manganese, Nucleophilic reactions",

author = "Jamespandi Annaraj and Jaeheung Cho and Lee, {Yong Min} and Kim, {Sung Yeon} and Reza Latifi and {De Visser}, {Sam P.} and Wonwoo Nam",

year = "2009",

month = may,

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doi = "10.1002/anie.200900118",

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journal = "Angewandte Chemie - International Edition",

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T1 - Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

AU - Annaraj, Jamespandi

AU - Cho, Jaeheung

AU - Lee, Yong Min

AU - Kim, Sung Yeon

AU - Latifi, Reza

AU - De Visser, Sam P.

AU - Nam, Wonwoo

PY - 2009/5/25

Y1 - 2009/5/25

N2 - The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Axial ligand effects

KW - Bioinorganic chemistry

KW - Enzyme models

KW - Manganese

KW - Nucleophilic reactions

U2 - 10.1002/anie.200900118

DO - 10.1002/anie.200900118

M3 - Article

SN - 1433-7851

VL - 48

SP - 4150

EP - 4153

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

Abstract

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Datasets

CCDC 715699: Experimental Crystal Structure Determination

Cite this