Structural isomerism in R3PSe(Ph)I compounds: The ionic structure of [(Me2N)3PSePh]I

Stephen M. Godfrey; Ruth T A Ollerenshaw; Robin G. Pritchard; Claire L. Richards

doi:10.1039/b100882j

Structural isomerism in R3PSe(Ph)I compounds: The ionic structure of [(Me2N)3PSePh]I

Stephen M. Godfrey, Ruth T A Ollerenshaw, Robin G. Pritchard, Claire L. Richards

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me 2N)3PSePh]I which contains a long Se-I contact, 3.825(1) Å, and a bent P-Se-I angle, 114.5(2)°.

Original language	English
Pages (from-to)	747-752
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/b100882j
Publication status	Published - 2001

Keywords

Crystal structure; Molecular structure (of tris(dimethylamino)phosphonium selenide iodides); Isomers (structural; of tris(dimethylamino)phosphonium selenide iodides)

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10.1039/b100882j

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abstract = "The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me 2N)3PSePh]I which contains a long Se-I contact, 3.825(1) {\AA}, and a bent P-Se-I angle, 114.5(2)°.",

keywords = "Crystal structure; Molecular structure (of tris(dimethylamino)phosphonium selenide iodides); Isomers (structural; of tris(dimethylamino)phosphonium selenide iodides)",

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journal = "Journal of the Chemical Society, Dalton Transactions",

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AU - Godfrey, Stephen M.

AU - Ollerenshaw, Ruth T A

AU - Pritchard, Robin G.

AU - Richards, Claire L.

PY - 2001

Y1 - 2001

N2 - The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me 2N)3PSePh]I which contains a long Se-I contact, 3.825(1) Å, and a bent P-Se-I angle, 114.5(2)°.

AB - The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me 2N)3PSePh]I which contains a long Se-I contact, 3.825(1) Å, and a bent P-Se-I angle, 114.5(2)°.

KW - Crystal structure; Molecular structure (of tris(dimethylamino)phosphonium selenide iodides); Isomers (structural; of tris(dimethylamino)phosphonium selenide iodides)

UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc5czdw&sid=DataCite

U2 - 10.1039/b100882j

DO - 10.1039/b100882j

M3 - Article

SN - 1477-9234

SP - 747

EP - 752

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 5

ER -

Structural isomerism in R3PSe(Ph)I compounds: The ionic structure of [(Me2N)3PSePh]I

Abstract

Keywords

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