Structure of ionic liquid-benzene mixtures

Maggel Deetlefs; Christopher Hardacre; Mark Nieuwenhuyzen; Oonagh Sheppard; Alan K. Soper

Structure of ionic liquid-benzene mixtures

Maggel Deetlefs^*, Christopher Hardacre, Mark Nieuwenhuyzen, Oonagh Sheppard, Alan K. Soper

^*Corresponding author for this work

Research output: Chapter in Book/Conference proceeding › Conference contribution › peer-review

Abstract

The solid state and liquid structure for mixtures of 1,3- dimethylimidazolium hexafluorophosphate with benzene have been elucidated using single crystal X-ray diffraction and neutron diffraction. In comparison with the structure of 1,3-dimethylimidazolium hexafluorophosphate in the absence of benzene, the addition of benzene is shown to significantly alter the ionic liquid structure, in particular in the cation-cation interactions. In the crystal structure, channels are formed which contain columns of benzene whereas in the liquid structure, the benzene is homogeneously distributed throughout the ionic liquid.

Original language	English
Title of host publication	Proceedings - Electrochemical Society
Pages	407-416
Number of pages	10
Volume	PV 2004-24
Publication status	Published - 2006
Event	206th ECS Meeting - Honolulu, HI, United States Duration: 3 Oct 2004 → 8 Oct 2004

Conference

Conference	206th ECS Meeting
Country/Territory	United States
City	Honolulu, HI
Period	3/10/04 → 8/10/04

Cite this

@inproceedings{4e50a02569a241e3bdeebf5c77a1e064,

title = "Structure of ionic liquid-benzene mixtures",

abstract = "The solid state and liquid structure for mixtures of 1,3- dimethylimidazolium hexafluorophosphate with benzene have been elucidated using single crystal X-ray diffraction and neutron diffraction. In comparison with the structure of 1,3-dimethylimidazolium hexafluorophosphate in the absence of benzene, the addition of benzene is shown to significantly alter the ionic liquid structure, in particular in the cation-cation interactions. In the crystal structure, channels are formed which contain columns of benzene whereas in the liquid structure, the benzene is homogeneously distributed throughout the ionic liquid.",

author = "Maggel Deetlefs and Christopher Hardacre and Mark Nieuwenhuyzen and Oonagh Sheppard and Soper, {Alan K.}",

year = "2006",

language = "English",

isbn = "9781566775144",

volume = "PV 2004-24",

pages = "407--416",

booktitle = "Proceedings - Electrochemical Society",

note = "206th ECS Meeting ; Conference date: 03-10-2004 Through 08-10-2004",

}

TY - GEN

T1 - Structure of ionic liquid-benzene mixtures

AU - Deetlefs, Maggel

AU - Hardacre, Christopher

AU - Nieuwenhuyzen, Mark

AU - Sheppard, Oonagh

AU - Soper, Alan K.

PY - 2006

Y1 - 2006

N2 - The solid state and liquid structure for mixtures of 1,3- dimethylimidazolium hexafluorophosphate with benzene have been elucidated using single crystal X-ray diffraction and neutron diffraction. In comparison with the structure of 1,3-dimethylimidazolium hexafluorophosphate in the absence of benzene, the addition of benzene is shown to significantly alter the ionic liquid structure, in particular in the cation-cation interactions. In the crystal structure, channels are formed which contain columns of benzene whereas in the liquid structure, the benzene is homogeneously distributed throughout the ionic liquid.

AB - The solid state and liquid structure for mixtures of 1,3- dimethylimidazolium hexafluorophosphate with benzene have been elucidated using single crystal X-ray diffraction and neutron diffraction. In comparison with the structure of 1,3-dimethylimidazolium hexafluorophosphate in the absence of benzene, the addition of benzene is shown to significantly alter the ionic liquid structure, in particular in the cation-cation interactions. In the crystal structure, channels are formed which contain columns of benzene whereas in the liquid structure, the benzene is homogeneously distributed throughout the ionic liquid.

UR - http://www.scopus.com/inward/record.url?scp=40249088903&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:40249088903

SN - 9781566775144

VL - PV 2004-24

SP - 407

EP - 416

BT - Proceedings - Electrochemical Society

T2 - 206th ECS Meeting

Y2 - 3 October 2004 through 8 October 2004

ER -

Structure of ionic liquid-benzene mixtures

Abstract

Conference

Other files and links

Fingerprint

Cite this