Studies on the additive fluoro-Pummerer reaction of phenylsulfanylated lactams with difluoroiodotoluene

Michael F. Greaney, William B. Motherwell, Derek A. Tocher

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Two fluorine atoms are effectively introduced to the 3- and 4-positions of sulfur-containing lactams through the action of the hypervalent iodoarene reagent difluoroiodotoluene (DFIT). The reaction proceeds through the intermediacy of the isolable α,β-unsaturated congener followed by an additive-Pummerer process. © 2001 Elsevier Science Ltd. All rights reserved.
    Original languageEnglish
    Pages (from-to)8523-8526
    Number of pages3
    JournalTetrahedron Letters
    Volume42
    Issue number48
    DOIs
    Publication statusPublished - 26 Nov 2001

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