Studies on the oxidation and fluorination of α-(phenylsulfanyl)acetamides using (difluoroiodo)toluene

Michael F Greaney; William B Motherwell

doi:10.1016/s0040-4039(00)00617-1

Studies on the oxidation and fluorination of α-(phenylsulfanyl)acetamides using (difluoroiodo)toluene

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Abstract

α-(Phenylthio)acetamides are fluorinated in the α-position when treated with 4-(difluoroiodo)toluene (DFIT) in a fluoro-Pummerer reaction. For N-phenylamides, an intramol. Friedel-Crafts reaction may compete and produce heterocycles. [on SciFinder(R)]

Original language	English
Pages (from-to)	4467-4470
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
DOIs	https://doi.org/10.1016/s0040-4039(00)00617-1
Publication status	Published - 2000

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title = "Studies on the oxidation and fluorination of α-(phenylsulfanyl)acetamides using (difluoroiodo)toluene",

abstract = "α-(Phenylthio)acetamides are fluorinated in the α-position when treated with 4-(difluoroiodo)toluene (DFIT) in a fluoro-Pummerer reaction. For N-phenylamides, an intramol. Friedel-Crafts reaction may compete and produce heterocycles. [on SciFinder(R)]",

author = "Greaney, {Michael F} and Motherwell, {William B}",

note = "CAPLUS AN 2000:431334(Journal)",

year = "2000",

doi = "10.1016/s0040-4039(00)00617-1",

language = "English",

volume = "41",

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journal = "Tetrahedron Letters",

issn = "1873-3581",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Studies on the oxidation and fluorination of α-(phenylsulfanyl)acetamides using (difluoroiodo)toluene

AU - Greaney, Michael F

AU - Motherwell, William B

N1 - CAPLUS AN 2000:431334(Journal)

PY - 2000

Y1 - 2000

N2 - α-(Phenylthio)acetamides are fluorinated in the α-position when treated with 4-(difluoroiodo)toluene (DFIT) in a fluoro-Pummerer reaction. For N-phenylamides, an intramol. Friedel-Crafts reaction may compete and produce heterocycles. [on SciFinder(R)]

AB - α-(Phenylthio)acetamides are fluorinated in the α-position when treated with 4-(difluoroiodo)toluene (DFIT) in a fluoro-Pummerer reaction. For N-phenylamides, an intramol. Friedel-Crafts reaction may compete and produce heterocycles. [on SciFinder(R)]

U2 - 10.1016/s0040-4039(00)00617-1

DO - 10.1016/s0040-4039(00)00617-1

M3 - Article

SN - 1873-3581

VL - 41

SP - 4467

EP - 4470

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

Studies on the oxidation and fluorination of α-(phenylsulfanyl)acetamides using (difluoroiodo)toluene

Abstract

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