Abstract
We present photoemission results for two systems, SrSn1-xSbxO3 and its row 6 analogue, BaPb1-xBix03. The variation in electronic structure as a function of composition is explored, particularly in the region of the metal-to-nonmetal transitions. In the case of the Sr system, dramatic surface segregation of Sb is revealed. This is analogous to that observed in Sn1-xSbx02. Resonant photoemission at oxygen and metal thresholds is used to explore the character of the valence band and gap states in these materials. © 1994.
Original language | English |
---|---|
Pages (from-to) | 1166-1171 |
Number of pages | 5 |
Journal | Surface Science |
Volume | 307-309 |
Publication status | Published - 20 Apr 1994 |