Surface electronic structure of complex B-metal perovskites

W. R. Flavell, D. R C Hoad, M. Mian, B. C. Morris, A. J. Roberts, M. M. Sarker, P. L. Wincott, D. Teehan, P. Bailey

    Research output: Contribution to journalArticlepeer-review

    Abstract

    We present photoemission results for two systems, SrSn1-xSbxO3 and its row 6 analogue, BaPb1-xBix03. The variation in electronic structure as a function of composition is explored, particularly in the region of the metal-to-nonmetal transitions. In the case of the Sr system, dramatic surface segregation of Sb is revealed. This is analogous to that observed in Sn1-xSbx02. Resonant photoemission at oxygen and metal thresholds is used to explore the character of the valence band and gap states in these materials. © 1994.
    Original languageEnglish
    Pages (from-to)1166-1171
    Number of pages5
    JournalSurface Science
    Volume307-309
    Publication statusPublished - 20 Apr 1994

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