Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations

Wen Zhen Fu; Han Qi Wang; Bei Wang; Hao Jie Duan; Xin Xin Cui; Wei Juan Wang; Zhe Guang Wang; Zhen Hua Zhang; Xiu Cun Liu; Yun Yin Niu

doi:10.1080/15533174.2011.555859

Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations

Wen Zhen Fu, Han Qi Wang, Bei Wang, Hao Jie Duan, Xin Xin Cui, Wei Juan Wang, Zhe Guang Wang, Zhen Hua Zhang, Xiu Cun Liu, Yun Yin Niu

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

Four supramolecular compounds, [(ZnCl4)(BPX)] 1, [(CdCl 4)(BPX)] 2, [(HgCl4)(BPX)] 3 and [Cu4(SCN) 6(BPX)]n4 (BPX = 1, 4-bis(pyridinium)xylol), were synthesized and characterized by IR spectrum and X-ray crystallography. The crystal structures of 1-3 show that they all crystallize in monoclinic systems with mononuclear tetrachlorometallate structure. Compound 4 crystallizes in triclinic system, space group P-1 in which four SCN-ions serve as bridging ligands to link four Cu(I) ions, giving rise to a 16-numbered ring. Many 16-membered rings are bridged by SCN- to form a one-dimensional chain structure.Furthermore, Cu-Cu bonds bridge two chain structures to form a one-dimensional complex chain structure. Copyright © Taylor & Francis Group, LLC.

Original language	English
Pages (from-to)	272-278
Number of pages	6
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	41
Issue number	3
DOIs	https://doi.org/10.1080/15533174.2011.555859
Publication status	Published - 2011

Keywords

1,4-bis(pyridinium)xylol
Coordination polymer
Crystal structure

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Fu, W. Z., Wang, H. Q., Wang, B., Duan, H. J., Cui, X. X., Wang, W. J., Wang, Z. G., Zhang, Z. H., Liu, X. C., & Niu, Y. Y. (2011). Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 41(3), 272-278. https://doi.org/10.1080/15533174.2011.555859

@article{492b7fb34d1549ecac3c64ce84c30e47,

title = "Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations",

abstract = "Four supramolecular compounds, [(ZnCl4)(BPX)] 1, [(CdCl 4)(BPX)] 2, [(HgCl4)(BPX)] 3 and [Cu4(SCN) 6(BPX)]n4 (BPX = 1, 4-bis(pyridinium)xylol), were synthesized and characterized by IR spectrum and X-ray crystallography. The crystal structures of 1-3 show that they all crystallize in monoclinic systems with mononuclear tetrachlorometallate structure. Compound 4 crystallizes in triclinic system, space group P-1 in which four SCN-ions serve as bridging ligands to link four Cu(I) ions, giving rise to a 16-numbered ring. Many 16-membered rings are bridged by SCN- to form a one-dimensional chain structure.Furthermore, Cu-Cu bonds bridge two chain structures to form a one-dimensional complex chain structure. Copyright {\textcopyright} Taylor & Francis Group, LLC.",

keywords = "1,4-bis(pyridinium)xylol, Coordination polymer, Crystal structure",

author = "Fu, {Wen Zhen} and Wang, {Han Qi} and Bei Wang and Duan, {Hao Jie} and Cui, {Xin Xin} and Wang, {Wei Juan} and Wang, {Zhe Guang} and Zhang, {Zhen Hua} and Liu, {Xiu Cun} and Niu, {Yun Yin}",

year = "2011",

doi = "10.1080/15533174.2011.555859",

language = "English",

volume = "41",

pages = "272--278",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

publisher = "Taylor & Francis",

number = "3",

}

Fu, WZ, Wang, HQ, Wang, B, Duan, HJ, Cui, XX, Wang, WJ, Wang, ZG, Zhang, ZH, Liu, XC & Niu, YY 2011, 'Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations', Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, vol. 41, no. 3, pp. 272-278. https://doi.org/10.1080/15533174.2011.555859

Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations. / Fu, Wen Zhen; Wang, Han Qi; Wang, Bei et al.
In: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, Vol. 41, No. 3, 2011, p. 272-278.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations

AU - Fu, Wen Zhen

AU - Wang, Han Qi

AU - Wang, Bei

AU - Duan, Hao Jie

AU - Cui, Xin Xin

AU - Wang, Wei Juan

AU - Wang, Zhe Guang

AU - Zhang, Zhen Hua

AU - Liu, Xiu Cun

AU - Niu, Yun Yin

PY - 2011

Y1 - 2011

N2 - Four supramolecular compounds, [(ZnCl4)(BPX)] 1, [(CdCl 4)(BPX)] 2, [(HgCl4)(BPX)] 3 and [Cu4(SCN) 6(BPX)]n4 (BPX = 1, 4-bis(pyridinium)xylol), were synthesized and characterized by IR spectrum and X-ray crystallography. The crystal structures of 1-3 show that they all crystallize in monoclinic systems with mononuclear tetrachlorometallate structure. Compound 4 crystallizes in triclinic system, space group P-1 in which four SCN-ions serve as bridging ligands to link four Cu(I) ions, giving rise to a 16-numbered ring. Many 16-membered rings are bridged by SCN- to form a one-dimensional chain structure.Furthermore, Cu-Cu bonds bridge two chain structures to form a one-dimensional complex chain structure. Copyright © Taylor & Francis Group, LLC.

AB - Four supramolecular compounds, [(ZnCl4)(BPX)] 1, [(CdCl 4)(BPX)] 2, [(HgCl4)(BPX)] 3 and [Cu4(SCN) 6(BPX)]n4 (BPX = 1, 4-bis(pyridinium)xylol), were synthesized and characterized by IR spectrum and X-ray crystallography. The crystal structures of 1-3 show that they all crystallize in monoclinic systems with mononuclear tetrachlorometallate structure. Compound 4 crystallizes in triclinic system, space group P-1 in which four SCN-ions serve as bridging ligands to link four Cu(I) ions, giving rise to a 16-numbered ring. Many 16-membered rings are bridged by SCN- to form a one-dimensional chain structure.Furthermore, Cu-Cu bonds bridge two chain structures to form a one-dimensional complex chain structure. Copyright © Taylor & Francis Group, LLC.

KW - 1,4-bis(pyridinium)xylol

KW - Coordination polymer

KW - Crystal structure

U2 - 10.1080/15533174.2011.555859

DO - 10.1080/15533174.2011.555859

M3 - Article

SN - 1553-3174

VL - 41

SP - 272

EP - 278

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 3

ER -

Fu WZ, Wang HQ, Wang B, Duan HJ, Cui XX, Wang WJ et al. Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry. 2011;41(3):272-278. doi: 10.1080/15533174.2011.555859

Syntheses and crystal structures of four supramolecular halides/pseudohalides: [(ZnCl4)(BPX)], [(CdCl4)(BPX)], [(HgCl4)(BPX)], and [Cu4(SCN)6(BPX)] n directed by 1,4-Bis(pyridinium)xylol cations

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Keywords

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