Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal–Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

Ying Fu; Jie Su; Sihai Yang; Zhibo Zou; Guobao Li; Fuhui Liao; Ming Xiong; Jianhua Lin

doi:10.1021/cg101610k

Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal–Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

Ying Fu, Jie Su, Sihai Yang, Zhibo Zou, Guobao Li, Fuhui Liao, Ming Xiong, Jianhua Lin

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

Three new compounds, [ZnNa(BTC)(H2O)2]·H2O (1), [Zn3Na2(BTC)2(HCOO)2(H2O)8] (2), and [Zn3Na(BTC)2(HCOO)(H2O)3]·2H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P1?, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)n for 1, (Na2Zn3O18)n for 2, or (NaZn3O14)n for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration?rehydration behaviors with a crystal-to-crystal transformation observed for 2.

Original language	English
Pages (from-to)	2243-2249
Number of pages	7
Journal	Crystal Growth & Design
Volume	11
Issue number	6
DOIs	https://doi.org/10.1021/cg101610k
Publication status	Published - 2011

Access to Document

10.1021/cg101610k

http://dx.doi.org/10.1021/cg101610k

CCDC 759102: Experimental Crystal Structure Determination
Fu, Y. (Contributor), Su, J. (Contributor), Yang, S. (Contributor), Zou, Z. (Contributor), Li, G. (Contributor), Liao, F. (Contributor), Xiong, M. (Contributor) & Lin, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/cctgx5b, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctgx5b&sid=DataCite
Dataset
CCDC 759101: Experimental Crystal Structure Determination
Fu, Y. (Contributor), Su, J. (Contributor), Yang, S. (Contributor), Zou, Z. (Contributor), Li, G. (Contributor), Liao, F. (Contributor), Xiong, M. (Contributor) & Lin, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/cctgx49, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctgx49&sid=DataCite
Dataset
CCDC 783280: Experimental Crystal Structure Determination
Fu, Y. (Contributor), Su, J. (Contributor), Yang, S. (Contributor), Zou, Z. (Contributor), Li, G. (Contributor), Liao, F. (Contributor), Xiong, M. (Contributor) & Lin, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccv9239, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccv9239&sid=DataCite
Dataset

Cite this

@article{28adba07c8ca4ea9a75abd61e59f4136,

title = "Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal–Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands",

abstract = "Three new compounds, [ZnNa(BTC)(H2O)2]·H2O (1), [Zn3Na2(BTC)2(HCOO)2(H2O)8] (2), and [Zn3Na(BTC)2(HCOO)(H2O)3]·2H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P1?, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)n for 1, (Na2Zn3O18)n for 2, or (NaZn3O14)n for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration?rehydration behaviors with a crystal-to-crystal transformation observed for 2.",

author = "Ying Fu and Jie Su and Sihai Yang and Zhibo Zou and Guobao Li and Fuhui Liao and Ming Xiong and Jianhua Lin",

year = "2011",

doi = "10.1021/cg101610k",

language = "English",

volume = "11",

pages = "2243--2249",

journal = "Crystal Growth & Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal–Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

AU - Fu, Ying

AU - Su, Jie

AU - Yang, Sihai

AU - Zou, Zhibo

AU - Li, Guobao

AU - Liao, Fuhui

AU - Xiong, Ming

AU - Lin, Jianhua

PY - 2011

Y1 - 2011

N2 - Three new compounds, [ZnNa(BTC)(H2O)2]·H2O (1), [Zn3Na2(BTC)2(HCOO)2(H2O)8] (2), and [Zn3Na(BTC)2(HCOO)(H2O)3]·2H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P1?, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)n for 1, (Na2Zn3O18)n for 2, or (NaZn3O14)n for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration?rehydration behaviors with a crystal-to-crystal transformation observed for 2.

AB - Three new compounds, [ZnNa(BTC)(H2O)2]·H2O (1), [Zn3Na2(BTC)2(HCOO)2(H2O)8] (2), and [Zn3Na(BTC)2(HCOO)(H2O)3]·2H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P1?, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)n for 1, (Na2Zn3O18)n for 2, or (NaZn3O14)n for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration?rehydration behaviors with a crystal-to-crystal transformation observed for 2.

U2 - 10.1021/cg101610k

DO - 10.1021/cg101610k

M3 - Article

VL - 11

SP - 2243

EP - 2249

JO - Crystal Growth & Design

JF - Crystal Growth & Design

SN - 1528-7483

IS - 6

ER -

Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal–Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

Abstract

Access to Document

Fingerprint

Datasets

CCDC 759102: Experimental Crystal Structure Determination

CCDC 759101: Experimental Crystal Structure Determination

CCDC 783280: Experimental Crystal Structure Determination

Cite this