Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework

S Yang; G B Li; W Liu; W Wang; Z M Yan; Y I Huang; F H Liao; J H Lin

doi:10.1021/ic900504m

Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework

S Yang, G B Li, W Liu, W Wang, Z M Yan, Y I Huang, F H Liao, J H Lin

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

(NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] (1) has been synthesized under hydrothermal conditions. The structure, the composition, and the thermal stability of 1 were determined by single-crystal X-ray diffraction; inductively coupled plasma-optical emission spectroscopy; IR spectroscopy; elemental analysis; thermogravimetric analysis-differential scanning calorimetry-mass spectrometry; and solid-state H-1, P-31, and F-19 NMR, and the phase purity of the bulk sample was checked by powder X-ray diffraction. Complex 1 is a fluorotitanophosphate having a unique lamella framework with both TiO5F octahedra and PO3OH tetrahedra on the surface of the layer, which leads to two different hydrogen bondings involving both P-OH and Ti-F groups.

Original language	English
Pages (from-to)	5449-5453
Number of pages	5
Journal	Inorganic Chemistry: including bioinorganic chemistry
Volume	48
Issue number	12
DOIs	https://doi.org/10.1021/ic900504m
Publication status	Published - 2009

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title = "Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework",

abstract = "(NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] (1) has been synthesized under hydrothermal conditions. The structure, the composition, and the thermal stability of 1 were determined by single-crystal X-ray diffraction; inductively coupled plasma-optical emission spectroscopy; IR spectroscopy; elemental analysis; thermogravimetric analysis-differential scanning calorimetry-mass spectrometry; and solid-state H-1, P-31, and F-19 NMR, and the phase purity of the bulk sample was checked by powder X-ray diffraction. Complex 1 is a fluorotitanophosphate having a unique lamella framework with both TiO5F octahedra and PO3OH tetrahedra on the surface of the layer, which leads to two different hydrogen bondings involving both P-OH and Ti-F groups.",

author = "S Yang and Li, {G B} and W Liu and W Wang and Yan, {Z M} and Huang, {Y I} and Liao, {F H} and Lin, {J H}",

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doi = "10.1021/ic900504m",

language = "English",

volume = "48",

pages = "5449--5453",

journal = "Inorganic Chemistry: including bioinorganic chemistry ",

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TY - JOUR

T1 - Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework

AU - Yang, S

AU - Li, G B

AU - Liu, W

AU - Wang, W

AU - Yan, Z M

AU - Huang, Y I

AU - Liao, F H

AU - Lin, J H

N1 - Times Cited: 0

PY - 2009

Y1 - 2009

N2 - (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] (1) has been synthesized under hydrothermal conditions. The structure, the composition, and the thermal stability of 1 were determined by single-crystal X-ray diffraction; inductively coupled plasma-optical emission spectroscopy; IR spectroscopy; elemental analysis; thermogravimetric analysis-differential scanning calorimetry-mass spectrometry; and solid-state H-1, P-31, and F-19 NMR, and the phase purity of the bulk sample was checked by powder X-ray diffraction. Complex 1 is a fluorotitanophosphate having a unique lamella framework with both TiO5F octahedra and PO3OH tetrahedra on the surface of the layer, which leads to two different hydrogen bondings involving both P-OH and Ti-F groups.

AB - (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] (1) has been synthesized under hydrothermal conditions. The structure, the composition, and the thermal stability of 1 were determined by single-crystal X-ray diffraction; inductively coupled plasma-optical emission spectroscopy; IR spectroscopy; elemental analysis; thermogravimetric analysis-differential scanning calorimetry-mass spectrometry; and solid-state H-1, P-31, and F-19 NMR, and the phase purity of the bulk sample was checked by powder X-ray diffraction. Complex 1 is a fluorotitanophosphate having a unique lamella framework with both TiO5F octahedra and PO3OH tetrahedra on the surface of the layer, which leads to two different hydrogen bondings involving both P-OH and Ti-F groups.

U2 - 10.1021/ic900504m

DO - 10.1021/ic900504m

M3 - Article

SN - 0020-1669

VL - 48

SP - 5449

EP - 5453

JO - Inorganic Chemistry: including bioinorganic chemistry

JF - Inorganic Chemistry: including bioinorganic chemistry

IS - 12

ER -

Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework

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