Synthesis and characterization of tetrathiafulvalenyl- and ferrocenyl-triphenylenes

Graeme Cooke; Abdulla Radhi; Neville Boden; Richard J Bushby; Zhibao Lu; Sarah Brown; Sarah L Heath

doi:10.1016/S0040-4020(00)00250-7

Synthesis and characterization of tetrathiafulvalenyl- and ferrocenyl-triphenylenes

Graeme Cooke, Abdulla Radhi, Neville Boden, Richard J Bushby, Zhibao Lu, Sarah Brown, Sarah L Heath

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis, electrochem. and mesogenic properties of novel tetrathiafulvalenyl- (e.g., I, R = R' = hexyl) and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivs. displaying a discotic mesophase. Soln. electrochem. of derivs. I (R = hexyl, R' = hexyl, Me) revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. [on SciFinder(R)]

Original language	English
Pages (from-to)	3385-3390
Number of pages	6
Journal	Tetrahedron
Volume	56
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4020(00)00250-7
Publication status	Published - 2000

Keywords

ferrocene carboxylic acid esterification reaction triphenylenehexanol
tetrathiafulvalene carboxylic acid esterification reaction triphenylenehexanol
triphenylene hexanol esterification reaction tetrathiafulvalene ferrocene carboxylic acid
ferrocenylacyl urea prepn crystal mol structure
alkyloxytriphenylene tetrathiafulvalene ferrocene adduct prepn electrochem redox

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10.1016/S0040-4020(00)00250-7

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Cite this

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title = "Synthesis and characterization of tetrathiafulvalenyl- and ferrocenyl-triphenylenes",

abstract = "The synthesis, electrochem. and mesogenic properties of novel tetrathiafulvalenyl- (e.g., I, R = R' = hexyl) and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivs. displaying a discotic mesophase. Soln. electrochem. of derivs. I (R = hexyl, R' = hexyl, Me) revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. [on SciFinder(R)]",

keywords = "ferrocene carboxylic acid esterification reaction triphenylenehexanol, tetrathiafulvalene carboxylic acid esterification reaction triphenylenehexanol, triphenylene hexanol esterification reaction tetrathiafulvalene ferrocene carboxylic acid, ferrocenylacyl urea prepn crystal mol structure, alkyloxytriphenylene tetrathiafulvalene ferrocene adduct prepn electrochem redox",

author = "Graeme Cooke and Abdulla Radhi and Neville Boden and Bushby, {Richard J} and Zhibao Lu and Sarah Brown and Heath, {Sarah L}",

note = "CAPLUS AN 2000:373667(Journal)",

year = "2000",

doi = "10.1016/S0040-4020(00)00250-7",

language = "English",

volume = "56",

pages = "3385--3390",

journal = "Tetrahedron",

issn = "1464-5416",

publisher = "Elsevier BV",

number = "21",

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TY - JOUR

T1 - Synthesis and characterization of tetrathiafulvalenyl- and ferrocenyl-triphenylenes

AU - Cooke, Graeme

AU - Radhi, Abdulla

AU - Boden, Neville

AU - Bushby, Richard J

AU - Lu, Zhibao

AU - Brown, Sarah

AU - Heath, Sarah L

N1 - CAPLUS AN 2000:373667(Journal)

PY - 2000

Y1 - 2000

N2 - The synthesis, electrochem. and mesogenic properties of novel tetrathiafulvalenyl- (e.g., I, R = R' = hexyl) and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivs. displaying a discotic mesophase. Soln. electrochem. of derivs. I (R = hexyl, R' = hexyl, Me) revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. [on SciFinder(R)]

AB - The synthesis, electrochem. and mesogenic properties of novel tetrathiafulvalenyl- (e.g., I, R = R' = hexyl) and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivs. displaying a discotic mesophase. Soln. electrochem. of derivs. I (R = hexyl, R' = hexyl, Me) revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. [on SciFinder(R)]

KW - ferrocene carboxylic acid esterification reaction triphenylenehexanol

KW - tetrathiafulvalene carboxylic acid esterification reaction triphenylenehexanol

KW - triphenylene hexanol esterification reaction tetrathiafulvalene ferrocene carboxylic acid

KW - ferrocenylacyl urea prepn crystal mol structure

KW - alkyloxytriphenylene tetrathiafulvalene ferrocene adduct prepn electrochem redox

U2 - 10.1016/S0040-4020(00)00250-7

DO - 10.1016/S0040-4020(00)00250-7

M3 - Article

SN - 1464-5416

VL - 56

SP - 3385

EP - 3390

JO - Tetrahedron

JF - Tetrahedron

IS - 21

ER -

Synthesis and characterization of tetrathiafulvalenyl- and ferrocenyl-triphenylenes

Abstract

Keywords

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