Synthesis and Full Characterisation of the First Discrete Binuclear Complex Featuring a Two-Electron (σ) μ2-κC:κC Bridging Cyanide

Martin Schroder; V Lippolis; M Schröder; A J Blake; P A Cooke; F Isaia; W-S Li

doi:10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D

Synthesis and Full Characterisation of the First Discrete Binuclear Complex Featuring a Two-Electron (σ) μ2-κC:κC Bridging Cyanide

Martin Schroder, V Lippolis, M Schröder, A J Blake, P A Cooke, F Isaia, W-S Li

Research output: Contribution to journal › Article › peer-review

Abstract

Nitrile-functionalised pendant-arm macrocycles have been used as supporting ligands for the first binuclear complex containing a discrete two-electron (σ) μ2-κC:κC symmetrically bridged CN− ligand (see example depicted; N= hatched circle, C[DOUBLE BOND]Open circle, S=shaded circle). A different coordination mode of the bridging CN− ligand is observed on changing the length of the aliphatic chain in the functionalised pendant arms of the macrocycle.

Original language	English
Pages (from-to)	1987-1991
Number of pages	5
Journal	Chemistry: A European Journal
Volume	5
Issue number	7
DOIs	https://doi.org/10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D
Publication status	Published - Jul 1999

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10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D

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title = "Synthesis and Full Characterisation of the First Discrete Binuclear Complex Featuring a Two-Electron (σ) μ2-κC:κC Bridging Cyanide",

abstract = "Nitrile-functionalised pendant-arm macrocycles have been used as supporting ligands for the first binuclear complex containing a discrete two-electron (σ) μ2-κC:κC symmetrically bridged CN− ligand (see example depicted; N= hatched circle, C[DOUBLE BOND]Open circle, S=shaded circle). A different coordination mode of the bridging CN− ligand is observed on changing the length of the aliphatic chain in the functionalised pendant arms of the macrocycle.",

author = "Martin Schroder and V Lippolis and M Schr{\"o}der and Blake, \{A J\} and Cooke, \{P A\} and F Isaia and W-S Li",

note = "cited By 16",

year = "1999",

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doi = "10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D",

language = "English",

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pages = "1987--1991",

journal = "Chemistry: A European Journal",

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TY - JOUR

T1 - Synthesis and Full Characterisation of the First Discrete Binuclear Complex Featuring a Two-Electron (σ) μ2-κC:κC Bridging Cyanide

AU - Schroder, Martin

AU - Lippolis, V

AU - Schröder, M

AU - Blake, A J

AU - Cooke, P A

AU - Isaia, F

AU - Li, W-S

N1 - cited By 16

PY - 1999/7

Y1 - 1999/7

N2 - Nitrile-functionalised pendant-arm macrocycles have been used as supporting ligands for the first binuclear complex containing a discrete two-electron (σ) μ2-κC:κC symmetrically bridged CN− ligand (see example depicted; N= hatched circle, C[DOUBLE BOND]Open circle, S=shaded circle). A different coordination mode of the bridging CN− ligand is observed on changing the length of the aliphatic chain in the functionalised pendant arms of the macrocycle.

AB - Nitrile-functionalised pendant-arm macrocycles have been used as supporting ligands for the first binuclear complex containing a discrete two-electron (σ) μ2-κC:κC symmetrically bridged CN− ligand (see example depicted; N= hatched circle, C[DOUBLE BOND]Open circle, S=shaded circle). A different coordination mode of the bridging CN− ligand is observed on changing the length of the aliphatic chain in the functionalised pendant arms of the macrocycle.

U2 - 10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D

DO - 10.1002/(SICI)1521-3765(19990702)5:7<1987::AID-CHEM1987>3.0.CO;2-D

M3 - Article

SN - 0947-6539

VL - 5

SP - 1987

EP - 1991

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

IS - 7

ER -

Synthesis and Full Characterisation of the First Discrete Binuclear Complex Featuring a Two-Electron (σ) μ2-κC:κC Bridging Cyanide

Abstract

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