Abstract
Trinuclear versus dinuclear heterodimetallic UVO2+⋯Co2+ complexes were selectively assembled via a cation–cation interaction by tuning the ligand. The trimeric complex 2, with a linear [Co–O[double bond, length as m-dash]U[double bond, length as m-dash]O–Co] core, exhibits magnetic exchange and slow relaxation with a reversal barrier of 30.5 ± 0.9 K providing the first example of a U–Co exchange-coupled SMM.
| Original language | English |
|---|---|
| Pages (from-to) | 5498-5502 |
| Journal | Dalton Transactions |
| Volume | 46 |
| Issue number | 17 |
| Early online date | 17 Jan 2017 |
| DOIs | |
| Publication status | Published - 17 Jan 2017 |
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Dive into the research topics of 'Synthesis and SMM behaviour of trinuclear versus dinuclear 3d–5f uranyl(V)–cobalt(II) cation–cation complexes'. Together they form a unique fingerprint.Datasets
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CCDC 1520434: Experimental Crystal Structure Determination
Chatelain, L. (Creator), Tuna, F. (Creator) & Pécaut, J. (Creator), Cambridge Crystallographic Data Centre, 2 Dec 2016
DOI: 10.5517/ccdc.csd.cc1n1483
Dataset
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CCDC 1520435: Experimental Crystal Structure Determination
Chatelain, L. (Creator), Tuna, F. (Creator), Pécaut, J. (Creator) & Mazzanti, M. (Creator), Cambridge Crystallographic Data Centre, 2 Dec 2016
DOI: 10.5517/ccdc.csd.cc1n1494
Dataset