Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand

Harry Adams; Mark R J Elsegood; David E Fenton; Sarah L Heath; Sara J Ryan

doi:10.1016/S1387-7003(99)00031-3

Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand

Harry Adams, Mark R J Elsegood, David E Fenton, Sarah L Heath, Sara J Ryan

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and crystal structure of [Ag2L](NO3)2 (L = a thiophene-linked Schiff base azacryptand, formed from 2,5-diformylthiophene and tren) are reported. The cryst. species is not stable at ambient temp. and the structure reveals a possible mechanism for the breakdown of the crystals. [Ag2L](NO3)2.2MeOH is triclinic, space group P̅1, Z = 2, R = 0.0427, Rw = 0.1203. [on SciFinder(R)]

Original language	English
Pages (from-to)	139-142
Number of pages	4
Journal	Inorg. Chem. Commun.
Volume	2
Issue number	4
DOIs	https://doi.org/10.1016/S1387-7003(99)00031-3
Publication status	Published - 1999

Keywords

silver thiophene linked Schiff azacryptand prepn structure
crystal structure silver thiophene linked Schiff azacryptand

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10.1016/S1387-7003(99)00031-3

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title = "Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand",

abstract = "The synthesis and crystal structure of [Ag2L](NO3)2 (L = a thiophene-linked Schiff base azacryptand, formed from 2,5-diformylthiophene and tren) are reported. The cryst. species is not stable at ambient temp. and the structure reveals a possible mechanism for the breakdown of the crystals. [Ag2L](NO3)2.2MeOH is triclinic, space group P̅1, Z = 2, R = 0.0427, Rw = 0.1203. [on SciFinder(R)]",

keywords = "silver thiophene linked Schiff azacryptand prepn structure, crystal structure silver thiophene linked Schiff azacryptand",

author = "Harry Adams and Elsegood, {Mark R J} and Fenton, {David E} and Heath, {Sarah L} and Ryan, {Sara J}",

note = "CAPLUS AN 1999:266555(Journal)",

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doi = "10.1016/S1387-7003(99)00031-3",

language = "English",

volume = "2",

pages = "139--142",

journal = "Inorg. Chem. Commun.",

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TY - JOUR

T1 - Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand

AU - Adams, Harry

AU - Elsegood, Mark R J

AU - Fenton, David E

AU - Heath, Sarah L

AU - Ryan, Sara J

N1 - CAPLUS AN 1999:266555(Journal)

PY - 1999

Y1 - 1999

N2 - The synthesis and crystal structure of [Ag2L](NO3)2 (L = a thiophene-linked Schiff base azacryptand, formed from 2,5-diformylthiophene and tren) are reported. The cryst. species is not stable at ambient temp. and the structure reveals a possible mechanism for the breakdown of the crystals. [Ag2L](NO3)2.2MeOH is triclinic, space group P̅1, Z = 2, R = 0.0427, Rw = 0.1203. [on SciFinder(R)]

AB - The synthesis and crystal structure of [Ag2L](NO3)2 (L = a thiophene-linked Schiff base azacryptand, formed from 2,5-diformylthiophene and tren) are reported. The cryst. species is not stable at ambient temp. and the structure reveals a possible mechanism for the breakdown of the crystals. [Ag2L](NO3)2.2MeOH is triclinic, space group P̅1, Z = 2, R = 0.0427, Rw = 0.1203. [on SciFinder(R)]

KW - silver thiophene linked Schiff azacryptand prepn structure

KW - crystal structure silver thiophene linked Schiff azacryptand

U2 - 10.1016/S1387-7003(99)00031-3

DO - 10.1016/S1387-7003(99)00031-3

M3 - Article

SN - 1387-7003

VL - 2

SP - 139

EP - 142

JO - Inorg. Chem. Commun.

JF - Inorg. Chem. Commun.

IS - 4

ER -

Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand

Abstract

Keywords

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