Synthesis and structure of a stable pentavalent-uranyl coordination polymer

Louise Natrajan; Fabien Burdet; Jacques Pécaut; Marinella Mazzanti

doi:10.1021/ja0609809

Synthesis and structure of a stable pentavalent-uranyl coordination polymer

Louise Natrajan, Fabien Burdet, Jacques Pécaut, Marinella Mazzanti

Research output: Contribution to journal › Article › peer-review

Abstract

The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry. Copyright © 2006 American Chemical Society.

Original language	English
Pages (from-to)	7152-7153
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	128
Issue number	22
DOIs	https://doi.org/10.1021/ja0609809
Publication status	Published - 7 Jun 2006

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10.1021/ja0609809

CCDC 615328: Experimental Crystal Structure Determination
Natrajan, L. (Contributor), Burdet, F. (Contributor), Pécaut, J. (Contributor) & Mazzanti, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2006
DOI: 10.5517/ccnn99w, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccnn99w&sid=DataCite
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Cite this

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title = "Synthesis and structure of a stable pentavalent-uranyl coordination polymer",

abstract = "The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry. Copyright {\textcopyright} 2006 American Chemical Society.",

author = "Louise Natrajan and Fabien Burdet and Jacques P{\'e}caut and Marinella Mazzanti",

year = "2006",

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doi = "10.1021/ja0609809",

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T1 - Synthesis and structure of a stable pentavalent-uranyl coordination polymer

AU - Natrajan, Louise

AU - Burdet, Fabien

AU - Pécaut, Jacques

AU - Mazzanti, Marinella

PY - 2006/6/7

Y1 - 2006/6/7

N2 - The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry. Copyright © 2006 American Chemical Society.

AB - The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry. Copyright © 2006 American Chemical Society.

U2 - 10.1021/ja0609809

DO - 10.1021/ja0609809

M3 - Article

SN - 0002-7863

VL - 128

SP - 7152

EP - 7153

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

Synthesis and structure of a stable pentavalent-uranyl coordination polymer

Abstract

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Datasets

CCDC 615328: Experimental Crystal Structure Determination

Cite this