Abstract
A nonmetal pentaborate [C2H10N2][B5O8(OH)] (I) was synthesized by a solvothermal method at 150 degrees C and characterized by elemental analysis, IR, thermogravimetric analysis, and X-ray diffraction. The structure of I was determined by a single-crystal technique. It crystallizes in the monoclinic system with space group Cc, a = 6.7085 (13) angstrom, b = 11.437(2) angstrom, c = 12.530(3) angstrom, and beta = 95.41(3)degrees. Powder second-harmonic generation (SHG) efficiency measurements with Nd:YAG laser (1064 nm) radiation show that [C2H10N2][B5O8(OH)] has a SHG efficiency approximately 1.2 times of that of potassium dihydrogen phosphate (KDP).
| Original language | English |
|---|---|
| Pages (from-to) | 1246-1250 |
| Number of pages | 5 |
| Journal | Crystal Growth & Design |
| Volume | 7 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2007 |
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CCDC 620021: Experimental Crystal Structure Determination
Yang, S. (Contributor), Li, G. B. (Contributor), Tian, S. J. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccnt5p9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccnt5p9&sid=DataCite
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CCDC 617384: Experimental Crystal Structure Determination
Yang, S. (Contributor), Li, G. B. (Contributor), Tian, S. J. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccnqfmd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccnqfmd&sid=DataCite
Dataset