Synthesis and structure of cationic guanidinate-bridged bimetallic {Li 7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions

Daniel Woodruff; Michael Bodensteiner; Daniel O. Sells; Richard E P Winpenny; Richard A. Layfield

doi:10.1039/c1dt10999e

Synthesis and structure of cationic guanidinate-bridged bimetallic {Li 7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions

Daniel Woodruff, Michael Bodensteiner, Daniel O. Sells, Richard E P Winpenny, Richard A. Layfield

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of the heteroleptic lithium amide [Li3(μ-hmds) 2(μ,μ-hpp)] (1), where [hmds]- = hexamethyldisilazide and [hpp]- = hexahydropyrimidopyrimidide, with MnCl2, CoCl2 or ZnBr2 result in the formation of the separated ion-pairs [MLi7(μ8-O)(μ,μ-hpp) 6]+[A]-, which each consist of a {MLi 7} oxo-centred cube structural motif (M = Mn 2, Co 4, Zn 5), with each face of the cube being bridged by an [hpp]- ligand. In the case of M = Mn and Co, the counter ion, [A]-, is the pentagonal anionic inverse crown [{Li(μ-hmds)}5(μ5-Cl)]- (3), whereas the reaction with M = Zn produces the known tris-amido zincate [Zn(hmds)3]- counter anion. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	10918-10923
Number of pages	5
Journal	Dalton Transactions
Volume	40
Issue number	41
DOIs	https://doi.org/10.1039/c1dt10999e
Publication status	Published - 7 Nov 2011

Access to Document

10.1039/c1dt10999e

CCDC 815987: Experimental Crystal Structure Determination
Woodruff, D. (Contributor), Bodensteiner, M. (Contributor), Sells, D. O. (Contributor), Winpenny, R. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwd35j, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwd35j&sid=DataCite
Dataset
CCDC 827194: Experimental Crystal Structure Determination
Woodruff, D. (Contributor), Bodensteiner, M. (Contributor), Sells, D. O. (Contributor), Winpenny, R. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwrrp1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwrrp1&sid=DataCite
Dataset
CCDC 827193: Experimental Crystal Structure Determination
Woodruff, D. (Contributor), Bodensteiner, M. (Contributor), Sells, D. O. (Contributor), Winpenny, R. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwrrn0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwrrn0&sid=DataCite
Dataset

Cite this

@article{f33d14e1f25d441ca5c808049ecadb20,

title = "Synthesis and structure of cationic guanidinate-bridged bimetallic {Li 7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions",

abstract = "The reactions of the heteroleptic lithium amide [Li3(μ-hmds) 2(μ,μ-hpp)] (1), where [hmds]- = hexamethyldisilazide and [hpp]- = hexahydropyrimidopyrimidide, with MnCl2, CoCl2 or ZnBr2 result in the formation of the separated ion-pairs [MLi7(μ8-O)(μ,μ-hpp) 6]+[A]-, which each consist of a {MLi 7} oxo-centred cube structural motif (M = Mn 2, Co 4, Zn 5), with each face of the cube being bridged by an [hpp]- ligand. In the case of M = Mn and Co, the counter ion, [A]-, is the pentagonal anionic inverse crown [{Li(μ-hmds)}5(μ5-Cl)]- (3), whereas the reaction with M = Zn produces the known tris-amido zincate [Zn(hmds)3]- counter anion. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Daniel Woodruff and Michael Bodensteiner and Sells, {Daniel O.} and Winpenny, {Richard E P} and Layfield, {Richard A.}",

year = "2011",

month = nov,

day = "7",

doi = "10.1039/c1dt10999e",

language = "English",

volume = "40",

pages = "10918--10923",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "41",

}

TY - JOUR

T1 - Synthesis and structure of cationic guanidinate-bridged bimetallic {Li 7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions

AU - Woodruff, Daniel

AU - Bodensteiner, Michael

AU - Sells, Daniel O.

AU - Winpenny, Richard E P

AU - Layfield, Richard A.

PY - 2011/11/7

Y1 - 2011/11/7

N2 - The reactions of the heteroleptic lithium amide [Li3(μ-hmds) 2(μ,μ-hpp)] (1), where [hmds]- = hexamethyldisilazide and [hpp]- = hexahydropyrimidopyrimidide, with MnCl2, CoCl2 or ZnBr2 result in the formation of the separated ion-pairs [MLi7(μ8-O)(μ,μ-hpp) 6]+[A]-, which each consist of a {MLi 7} oxo-centred cube structural motif (M = Mn 2, Co 4, Zn 5), with each face of the cube being bridged by an [hpp]- ligand. In the case of M = Mn and Co, the counter ion, [A]-, is the pentagonal anionic inverse crown [{Li(μ-hmds)}5(μ5-Cl)]- (3), whereas the reaction with M = Zn produces the known tris-amido zincate [Zn(hmds)3]- counter anion. © 2011 The Royal Society of Chemistry.

AB - The reactions of the heteroleptic lithium amide [Li3(μ-hmds) 2(μ,μ-hpp)] (1), where [hmds]- = hexamethyldisilazide and [hpp]- = hexahydropyrimidopyrimidide, with MnCl2, CoCl2 or ZnBr2 result in the formation of the separated ion-pairs [MLi7(μ8-O)(μ,μ-hpp) 6]+[A]-, which each consist of a {MLi 7} oxo-centred cube structural motif (M = Mn 2, Co 4, Zn 5), with each face of the cube being bridged by an [hpp]- ligand. In the case of M = Mn and Co, the counter ion, [A]-, is the pentagonal anionic inverse crown [{Li(μ-hmds)}5(μ5-Cl)]- (3), whereas the reaction with M = Zn produces the known tris-amido zincate [Zn(hmds)3]- counter anion. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c1dt10999e

DO - 10.1039/c1dt10999e

M3 - Article

SN - 1477-9234

VL - 40

SP - 10918

EP - 10923

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

Synthesis and structure of cationic guanidinate-bridged bimetallic {Li 7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions

Abstract

Access to Document

Fingerprint

Datasets

CCDC 815987: Experimental Crystal Structure Determination

CCDC 827194: Experimental Crystal Structure Determination

CCDC 827193: Experimental Crystal Structure Determination

Cite this