Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase

Martin Schroder; N D J Branscombe; L Ruiz-Ramirez; M Schröder; A J Blake; A Marin-Becerra; W-S Li; S Parsons

doi:10.1039/CC9960002573

Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase

Martin Schroder, N D J Branscombe, L Ruiz-Ramirez, M Schröder, A J Blake, A Marin-Becerra, W-S Li, S Parsons

Research output: Contribution to journal › Article › peer-review

Abstract

The tetranuclear cluster [Zn2L(µ-OH)]2[ClO4]2·2H2O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear ZnII units linked by two µ-hydroxy bridges; the structure of the CuII complex [Cu2L(HOMe)2](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu⋯Cu separation of 3.264(2)Å.

Original language	English
Pages (from-to)	2573-2574
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/CC9960002573
Publication status	Published - 1996

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Schroder, M., Branscombe, N. D. J., Ruiz-Ramirez, L., Schröder, M., Blake, A. J., Marin-Becerra, A., Li, W.-S., & Parsons, S. (1996). Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase. Chemical Communications, (22), 2573-2574. https://doi.org/10.1039/CC9960002573

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title = "Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase",

abstract = "The tetranuclear cluster [Zn2L(µ-OH)]2[ClO4]2·2H2O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear ZnII units linked by two µ-hydroxy bridges; the structure of the CuII complex [Cu2L(HOMe)2](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu⋯Cu separation of 3.264(2){\AA}.",

author = "Martin Schroder and Branscombe, {N D J} and L Ruiz-Ramirez and M Schr{\"o}der and Blake, {A J} and A Marin-Becerra and W-S Li and S Parsons",

note = "cited By 54",

year = "1996",

doi = "10.1039/CC9960002573",

language = "English",

pages = "2573--2574",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "22",

}

Schroder, M, Branscombe, NDJ, Ruiz-Ramirez, L, Schröder, M, Blake, AJ, Marin-Becerra, A, Li, W-S & Parsons, S 1996, 'Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase', Chemical Communications, no. 22, pp. 2573-2574. https://doi.org/10.1039/CC9960002573

Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase. / Schroder, Martin; Branscombe, N D J; Ruiz-Ramirez, L et al.
In: Chemical Communications, No. 22, 1996, p. 2573-2574.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase

AU - Schroder, Martin

AU - Branscombe, N D J

AU - Ruiz-Ramirez, L

AU - Schröder, M

AU - Blake, A J

AU - Marin-Becerra, A

AU - Li, W-S

AU - Parsons, S

N1 - cited By 54

PY - 1996

Y1 - 1996

N2 - The tetranuclear cluster [Zn2L(µ-OH)]2[ClO4]2·2H2O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear ZnII units linked by two µ-hydroxy bridges; the structure of the CuII complex [Cu2L(HOMe)2](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu⋯Cu separation of 3.264(2)Å.

AB - The tetranuclear cluster [Zn2L(µ-OH)]2[ClO4]2·2H2O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear ZnII units linked by two µ-hydroxy bridges; the structure of the CuII complex [Cu2L(HOMe)2](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu⋯Cu separation of 3.264(2)Å.

U2 - 10.1039/CC9960002573

DO - 10.1039/CC9960002573

M3 - Article

SN - 1364-548X

SP - 2573

EP - 2574

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Schroder M, Branscombe NDJ, Ruiz-Ramirez L, Schröder M, Blake AJ, Marin-Becerra A et al. Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear CuA site in cytochrome c oxidase and N2O reductase. Chemical Communications. 1996;(22):2573-2574. doi: 10.1039/CC9960002573