Synthesis and structure of the novel "paddle-wheel" complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF]

Richard A. Layfield; Mary McPartlin; Dominic S. Wright

doi:10.1021/om030126f

Synthesis and structure of the novel "paddle-wheel" complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF]

Richard A. Layfield
, Mary McPartlin
, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction between CpPbCl and CpthfK-(THF) (1:2 equiv, Cpthf = 2-tetrahydrofurfurylcyclopentadienyl) in THF solvent unexpected results in formation of the homoleptic paddle-wheel complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF] (3). The outcome of the reaction is likely to be due to a solvent-promoted ligand redistribution process.

Original language	English
Pages (from-to)	2528-2530
Number of pages	2
Journal	Organometallics
Volume	22
Issue number	12
DOIs	https://doi.org/10.1021/om030126f
Publication status	Published - 9 Jun 2003

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title = "Synthesis and structure of the novel {"}paddle-wheel{"} complex [\{(η5-Cp)2Pb(μ:η5-Cp)K\{\.}}2THF]",

abstract = "The reaction between CpPbCl and CpthfK-(THF) (1:2 equiv, Cpthf = 2-tetrahydrofurfurylcyclopentadienyl) in THF solvent unexpected results in formation of the homoleptic paddle-wheel complex [\{(η5-Cp)2Pb(μ:η5-Cp)K\{\.}}2THF] (3). The outcome of the reaction is likely to be due to a solvent-promoted ligand redistribution process.",

author = "Layfield, \{Richard A.\} and Mary McPartlin and Wright, \{Dominic S.\}",

year = "2003",

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doi = "10.1021/om030126f",

language = "English",

volume = "22",

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journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Synthesis and structure of the novel "paddle-wheel" complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF]

AU - Layfield, Richard A.

AU - McPartlin, Mary

AU - Wright, Dominic S.

PY - 2003/6/9

Y1 - 2003/6/9

N2 - The reaction between CpPbCl and CpthfK-(THF) (1:2 equiv, Cpthf = 2-tetrahydrofurfurylcyclopentadienyl) in THF solvent unexpected results in formation of the homoleptic paddle-wheel complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF] (3). The outcome of the reaction is likely to be due to a solvent-promoted ligand redistribution process.

AB - The reaction between CpPbCl and CpthfK-(THF) (1:2 equiv, Cpthf = 2-tetrahydrofurfurylcyclopentadienyl) in THF solvent unexpected results in formation of the homoleptic paddle-wheel complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF] (3). The outcome of the reaction is likely to be due to a solvent-promoted ligand redistribution process.

U2 - 10.1021/om030126f

DO - 10.1021/om030126f

M3 - Article

SN - 0276-7333

VL - 22

SP - 2528

EP - 2530

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Synthesis and structure of the novel "paddle-wheel" complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF]

Abstract

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