Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>5</inf>R <inf>5</inf>)]+ (M = Rh or Ir)

A.S. Romanov; D.V. Muratov; P.V. Petrovskii; M.Yu Antipin; W. Siebert; A.R. Kudinov

Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>5</inf>R <inf>5</inf>)]+ (M = Rh or Ir)

A.S. Romanov, D.V. Muratov, P.V. Petrovskii, M.Yu Antipin, W. Siebert, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with the halide complexes [CpMI2]2 or [Cp*MCl2]2 (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal—diborolyl bond in these complexes was analyzed using the energy decomposition scheme.

Original language	English
Pages (from-to)	594-599
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	58
Issue number	3
Publication status	Published - Mar 2009

Keywords

Boron-containing heterocycles
Cobalt
Iridium
Rhodium
Sandwich compounds
Triple-decker complexes

Cite this

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title = "Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R 5)]+ (M = Rh or Ir)",

abstract = "The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with the halide complexes [CpMI2]2 or [Cp*MCl2]2 (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal—diborolyl bond in these complexes was analyzed using the energy decomposition scheme.",

keywords = "Boron-containing heterocycles, Cobalt, Iridium, Rhodium, Sandwich compounds, Triple-decker complexes",

author = "A.S. Romanov and D.V. Muratov and P.V. Petrovskii and M.Yu Antipin and W. Siebert and A.R. Kudinov",

year = "2009",

month = mar,

language = "English",

volume = "58",

pages = "594--599",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "3",

}

Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>5</inf>R <inf>5</inf>)]+ (M = Rh or Ir). / Romanov, A.S.; Muratov, D.V.; Petrovskii, P.V. et al.
In: Russian Chemical Bulletin, Vol. 58, No. 3, 03.2009, p. 594-599.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R 5)]+ (M = Rh or Ir)

AU - Romanov, A.S.

AU - Muratov, D.V.

AU - Petrovskii, P.V.

AU - Antipin, M.Yu

AU - Siebert, W.

AU - Kudinov, A.R.

PY - 2009/3

Y1 - 2009/3

N2 - The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with the halide complexes [CpMI2]2 or [Cp*MCl2]2 (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal—diborolyl bond in these complexes was analyzed using the energy decomposition scheme.

AB - The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with the halide complexes [CpMI2]2 or [Cp*MCl2]2 (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal—diborolyl bond in these complexes was analyzed using the energy decomposition scheme.

KW - Boron-containing heterocycles

KW - Cobalt

KW - Iridium

KW - Rhodium

KW - Sandwich compounds

KW - Triple-decker complexes

UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-77953559358&partnerID=MN8TOARS

M3 - Article

SN - 1066-5285

VL - 58

SP - 594

EP - 599

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 3

ER -

Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>5</inf>R <inf>5</inf>)]<sup>+</sup> (M = Rh or Ir)

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