Synthesis and structures of copper(II) anion-bridged aggregates and chains: control over molecular shape

Anne C Deveson; Sarah L Heath; Charles J Harding; Annie K Powell

Synthesis and structures of copper(II) anion-bridged aggregates and chains: control over molecular shape

Anne C Deveson, Sarah L Heath, Charles J Harding, Annie K Powell

Research output: Contribution to journal › Article › peer-review

Abstract

Di-2-pyridyl ketone (dpk) can complex metal ions in its activated [(NC5H4)2C(OR)(OH)] or nonactivated form. In its activated form it displays a dinucleating behavior as manifested by [{Cu2[(NC5H4)2C(OEt)O]Cl3(EtOH)}2] and [{Cu2[(NC5H4)2C(OMe)O]Cl3}∞] (which also possess halide bridges). These compds. were prepd. and structurally characterized using single-crystal x-ray diffraction. In its nonactivated form its acts as a simple bidentate chelate. The complex [{Cu(dpk)(NO3)2}∞] was prepd. and its x-ray anal. revealed an anion-bridged structure where bridging nitrato groups link the copper centers. The π-stacking arrangements of these compds. are also considered. [on SciFinder(R)]

Original language	English
Pages (from-to)	3173-3178
Number of pages	6
Journal	J. Chem. Soc., Dalton Trans.
Issue number	15
Publication status	Published - 1996

Keywords

crystal structure copper pyridyl ketone alkoxymethanol
copper pyridyl ketone alkoxymethanol prepn structure

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title = "Synthesis and structures of copper(II) anion-bridged aggregates and chains: control over molecular shape",

abstract = "Di-2-pyridyl ketone (dpk) can complex metal ions in its activated [(NC5H4)2C(OR)(OH)] or nonactivated form. In its activated form it displays a dinucleating behavior as manifested by [{Cu2[(NC5H4)2C(OEt)O]Cl3(EtOH)}2] and [{Cu2[(NC5H4)2C(OMe)O]Cl3}∞] (which also possess halide bridges). These compds. were prepd. and structurally characterized using single-crystal x-ray diffraction. In its nonactivated form its acts as a simple bidentate chelate. The complex [{Cu(dpk)(NO3)2}∞] was prepd. and its x-ray anal. revealed an anion-bridged structure where bridging nitrato groups link the copper centers. The π-stacking arrangements of these compds. are also considered. [on SciFinder(R)]",

keywords = "crystal structure copper pyridyl ketone alkoxymethanol, copper pyridyl ketone alkoxymethanol prepn structure",

author = "Deveson, {Anne C} and Heath, {Sarah L} and Harding, {Charles J} and Powell, {Annie K}",

note = "CAPLUS AN 1996:522944(Journal)",

year = "1996",

language = "English",

pages = "3173--3178",

journal = "J. Chem. Soc., Dalton Trans.",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "15",

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TY - JOUR

T1 - Synthesis and structures of copper(II) anion-bridged aggregates and chains: control over molecular shape

AU - Deveson, Anne C

AU - Heath, Sarah L

AU - Harding, Charles J

AU - Powell, Annie K

N1 - CAPLUS AN 1996:522944(Journal)

PY - 1996

Y1 - 1996

N2 - Di-2-pyridyl ketone (dpk) can complex metal ions in its activated [(NC5H4)2C(OR)(OH)] or nonactivated form. In its activated form it displays a dinucleating behavior as manifested by [{Cu2[(NC5H4)2C(OEt)O]Cl3(EtOH)}2] and [{Cu2[(NC5H4)2C(OMe)O]Cl3}∞] (which also possess halide bridges). These compds. were prepd. and structurally characterized using single-crystal x-ray diffraction. In its nonactivated form its acts as a simple bidentate chelate. The complex [{Cu(dpk)(NO3)2}∞] was prepd. and its x-ray anal. revealed an anion-bridged structure where bridging nitrato groups link the copper centers. The π-stacking arrangements of these compds. are also considered. [on SciFinder(R)]

AB - Di-2-pyridyl ketone (dpk) can complex metal ions in its activated [(NC5H4)2C(OR)(OH)] or nonactivated form. In its activated form it displays a dinucleating behavior as manifested by [{Cu2[(NC5H4)2C(OEt)O]Cl3(EtOH)}2] and [{Cu2[(NC5H4)2C(OMe)O]Cl3}∞] (which also possess halide bridges). These compds. were prepd. and structurally characterized using single-crystal x-ray diffraction. In its nonactivated form its acts as a simple bidentate chelate. The complex [{Cu(dpk)(NO3)2}∞] was prepd. and its x-ray anal. revealed an anion-bridged structure where bridging nitrato groups link the copper centers. The π-stacking arrangements of these compds. are also considered. [on SciFinder(R)]

KW - crystal structure copper pyridyl ketone alkoxymethanol

KW - copper pyridyl ketone alkoxymethanol prepn structure

M3 - Article

SN - 0300-9246

SP - 3173

EP - 3178

JO - J. Chem. Soc., Dalton Trans.

JF - J. Chem. Soc., Dalton Trans.

IS - 15

ER -

Synthesis and structures of copper(II) anion-bridged aggregates and chains: control over molecular shape

Abstract

Keywords

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