Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C <inf>3</inf>B <inf>2</inf>Me <inf>5</inf>)MX <inf>2</inf>L (M = Rh and Ir; X = Cl and Br; L = Me <inf>2</inf>SO and PPh <inf>3</inf>)

A.S. Romanov, D.V. Muratov, M.Y. Antipin, W. Siebert, A.R. Kudinov

Research output: Contribution to journalArticlepeer-review

Abstract

The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5–12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5–12 were confirmed by X-ray diffraction.
Original languageEnglish
Pages (from-to)136-140
Number of pages5
JournalJournal of Organometallic Chemistry
Volume715
DOIs
Publication statusPublished - 15 Sept 2012

Keywords

  • Boron
  • Cobalt
  • Heterocycles
  • Rhodium
  • Iridium
  • Triple-decker complexes

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