Abstract
The molybdenum dithiocarbamato complexes [Mo(S2CNnBu2)4] (1), [Mo2S4(S2CN nBu2)2.1/2H2O (2) have been synthesized and characterized. Single crystal X-ray studies of (1) showed that molybdenum atom is coordinated to eight sulfur atoms in dodecahedron geometry and the bond lengths and bond angles fall within the range of values expected. In (2) the molybdenum atoms are coordinated to five sulfur atoms in a distorted square pyramid. © 2008 Taylor & Francis.
| Original language | English |
|---|---|
| Pages (from-to) | 79-84 |
| Number of pages | 5 |
| Journal | Journal of Coordination Chemistry |
| Volume | 61 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2008 |
Keywords
- Crystal structures
- Dithiocarbamates
- Molybdenum
- Molybdenum sulfide
- Precursors
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Dive into the research topics of 'Synthesis and X-ray single crystal structures of [Mo(S2CN nBu2)4] and [Mo2S4(S 2CNnBu2)2]·1/2 H2O'. Together they form a unique fingerprint.Datasets
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CCDC 649490: Experimental Crystal Structure Determination
Malik, M. (Contributor), O'Brien, P. (Contributor), Adeogun, A. (Contributor), Helliwell, M. (Contributor) & Raftery, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccpsv9l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpsv9l&sid=DataCite
Dataset
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CCDC 263010: Experimental Crystal Structure Determination
Malik, M. (Contributor), O'Brien, P. (Contributor), Adeogun, A. (Contributor), Helliwell, M. (Contributor) & Raftery, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc8tp6y, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8tp6y&sid=DataCite
Dataset