Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C <inf>3</inf>B<inf>2</inf>Me5)Ru(arene)]+

D.V. Muratov; A.S. Romanov; P.V. Petrovskii; M.Yu Antipin; A.R. Kudinov

doi:10.1007/s11172-009-0123-2

Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C <inf>3</inf>B<inf>2</inf>Me5)Ru(arene)]+

D.V. Muratov, A.S. Romanov, P.V. Petrovskii, M.Yu Antipin, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Cationic triple-decker complexes [CpCo(1,3-C3B 2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis.

Original language	English
Pages (from-to)	964-967
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	58
Issue number	5
DOIs	https://doi.org/10.1007/s11172-009-0123-2
Publication status	Published - May 2009

Keywords

Boron-containing heterocycles
Cobalt
Ruthenium
Sandwich compounds
Triple-decker complexes

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10.1007/s11172-009-0123-2

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title = "Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C 3B2Me5)Ru(arene)]+",

abstract = "Cationic triple-decker complexes [CpCo(1,3-C3B 2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis. ",

keywords = "Boron-containing heterocycles, Cobalt, Ruthenium, Sandwich compounds, Triple-decker complexes",

author = "D.V. Muratov and A.S. Romanov and P.V. Petrovskii and M.Yu Antipin and A.R. Kudinov",

year = "2009",

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doi = "10.1007/s11172-009-0123-2",

language = "English",

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T1 - Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C 3B2Me5)Ru(arene)]+

AU - Muratov, D.V.

AU - Romanov, A.S.

AU - Petrovskii, P.V.

AU - Antipin, M.Yu

AU - Kudinov, A.R.

PY - 2009/5

Y1 - 2009/5

N2 - Cationic triple-decker complexes [CpCo(1,3-C3B 2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis.

AB - Cationic triple-decker complexes [CpCo(1,3-C3B 2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis.

KW - Boron-containing heterocycles

KW - Cobalt

KW - Ruthenium

KW - Sandwich compounds

KW - Triple-decker complexes

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DO - 10.1007/s11172-009-0123-2

M3 - Article

SN - 1066-5285

VL - 58

SP - 964

EP - 967

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 5

ER -

Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C <inf>3</inf>B<inf>2</inf>Me5)Ru(arene)]+

Abstract

Keywords

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