Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks

Darren Dixon; Darren J. Dixon; Steven V. Ley; Sophie Lohmann; Tom D. Sheppard

doi:10.1055/s-2005-862361

Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks

Darren Dixon, Darren J. Dixon, Steven V. Ley, Sophie Lohmann, Tom D. Sheppard

Research output: Contribution to journal › Article › peer-review

Abstract

A stereoselective synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii is reported using diastereoselective alkylation and aldol reactions of butane-2,3-diacetal (BDA) desymmetrised glycolic acid building blocks as the key synthetic steps. © Georg Thieme Verlag Stuttgart.

Original language	English
Pages (from-to)	481-484
Number of pages	3
Journal	SYNLETT
Issue number	3
DOIs	https://doi.org/10.1055/s-2005-862361
Publication status	Published - 16 Feb 2005

Keywords

Acetals
Chiral auxiliaries
Pheromones
Sphingolipids
Stereoselective synthesis

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10.1055/s-2005-862361

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title = "Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks",

abstract = "A stereoselective synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii is reported using diastereoselective alkylation and aldol reactions of butane-2,3-diacetal (BDA) desymmetrised glycolic acid building blocks as the key synthetic steps. {\textcopyright} Georg Thieme Verlag Stuttgart.",

keywords = "Acetals, Chiral auxiliaries, Pheromones, Sphingolipids, Stereoselective synthesis",

author = "Darren Dixon and Dixon, {Darren J.} and Ley, {Steven V.} and Sophie Lohmann and Sheppard, {Tom D.}",

year = "2005",

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AU - Dixon, Darren

AU - Dixon, Darren J.

AU - Ley, Steven V.

AU - Lohmann, Sophie

AU - Sheppard, Tom D.

PY - 2005/2/16

Y1 - 2005/2/16

N2 - A stereoselective synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii is reported using diastereoselective alkylation and aldol reactions of butane-2,3-diacetal (BDA) desymmetrised glycolic acid building blocks as the key synthetic steps. © Georg Thieme Verlag Stuttgart.

AB - A stereoselective synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii is reported using diastereoselective alkylation and aldol reactions of butane-2,3-diacetal (BDA) desymmetrised glycolic acid building blocks as the key synthetic steps. © Georg Thieme Verlag Stuttgart.

KW - Acetals

KW - Chiral auxiliaries

KW - Pheromones

KW - Sphingolipids

KW - Stereoselective synthesis

UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc8n89g&sid=DataCite

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JF - SYNLETT

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ER -

Synthesis of a ceramide sphingolipid as a potential sex pheromone of the hair crab Erimacrus isenbeckii using butane-2,3-diacetal desymmetrised glycolic acid building blocks

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