Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>6</inf>H <inf>6</inf>)]<sup>2+</sup> (M = Rh, Ir)

A.S. Romanov; D.V. Muratov; M.Yu Antipin; A.R. Kudinov

doi:10.1007/s11172-009-0125-0

Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>6</inf>H <inf>6</inf>)]<sup>2+</sup> (M = Rh, Ir)

A.S. Romanov, D.V. Muratov, M.Yu Antipin, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Dicationic triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-C3B2Me5)MBr2]2 (M = Rh, Ir) with benzene in the presence of AgBF4. The structure of 3(BF4)2 was determined by X-ray diffraction analysis.

Original language	English
Pages (from-to)	971-973
Number of pages	3
Journal	Russian Chemical Bulletin
Volume	58
Issue number	5
DOIs	https://doi.org/10.1007/s11172-009-0125-0
Publication status	Published - May 2009

Keywords

Boron-containing heterocycles
Cobalt
Iridium
Rhodium
Sandwich compounds
Triple-decker complexes

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10.1007/s11172-009-0125-0

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title = "Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H 6)]2+ (M = Rh, Ir)",

abstract = "Dicationic triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-C3B2Me5)MBr2]2 (M = Rh, Ir) with benzene in the presence of AgBF4. The structure of 3(BF4)2 was determined by X-ray diffraction analysis.",

keywords = "Boron-containing heterocycles, Cobalt, Iridium, Rhodium, Sandwich compounds, Triple-decker complexes",

author = "A.S. Romanov and D.V. Muratov and M.Yu Antipin and A.R. Kudinov",

year = "2009",

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doi = "10.1007/s11172-009-0125-0",

language = "English",

volume = "58",

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T1 - Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H 6)]2+ (M = Rh, Ir)

AU - Romanov, A.S.

AU - Muratov, D.V.

AU - Antipin, M.Yu

AU - Kudinov, A.R.

PY - 2009/5

Y1 - 2009/5

N2 - Dicationic triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-C3B2Me5)MBr2]2 (M = Rh, Ir) with benzene in the presence of AgBF4. The structure of 3(BF4)2 was determined by X-ray diffraction analysis.

AB - Dicationic triple-decker complexes [CpCo(μ-1,3-C3B2Me5)M(C6H6)]2+ (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-C3B2Me5)MBr2]2 (M = Rh, Ir) with benzene in the presence of AgBF4. The structure of 3(BF4)2 was determined by X-ray diffraction analysis.

KW - Boron-containing heterocycles

KW - Cobalt

KW - Iridium

KW - Rhodium

KW - Sandwich compounds

KW - Triple-decker complexes

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DO - 10.1007/s11172-009-0125-0

M3 - Article

SN - 1066-5285

VL - 58

SP - 971

EP - 973

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 5

ER -

Synthesis of dicationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C<inf>3</inf>B<inf>2</inf>Me<inf>5</inf>)M(C<inf>6</inf>H <inf>6</inf>)]<sup>2+</sup> (M = Rh, Ir)

Abstract

Keywords

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