Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

D.V. Muratov; A.S. Romanov; P.V. Petrovskii; Z.A. Starikova; A.R. Kudinov

doi:10.1007/s11172-009-0124-1

Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

D.V. Muratov, A.S. Romanov, P.V. Petrovskii, Z.A. Starikova, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.

Original language	English
Pages (from-to)	968-970
Number of pages	3
Journal	Russian Chemical Bulletin
Volume	58
Issue number	5
DOIs	https://doi.org/10.1007/s11172-009-0124-1
Publication status	Published - 2009

Keywords

Boron-containing heterocycles
Cobalt
Iridium
Rhodium
Sandwich compounds

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10.1007/s11172-009-0124-1

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title = "Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand",

abstract = "Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.",

keywords = "Boron-containing heterocycles, Cobalt, Iridium, Rhodium, Sandwich compounds",

author = "D.V. Muratov and A.S. Romanov and P.V. Petrovskii and Z.A. Starikova and A.R. Kudinov",

year = "2009",

doi = "10.1007/s11172-009-0124-1",

language = "English",

volume = "58",

pages = "968--970",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

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TY - JOUR

T1 - Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

AU - Muratov, D.V.

AU - Romanov, A.S.

AU - Petrovskii, P.V.

AU - Starikova, Z.A.

AU - Kudinov, A.R.

PY - 2009

Y1 - 2009

N2 - Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.

AB - Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.

KW - Boron-containing heterocycles

KW - Cobalt

KW - Iridium

KW - Rhodium

KW - Sandwich compounds

UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-77955733350&partnerID=MN8TOARS

U2 - 10.1007/s11172-009-0124-1

DO - 10.1007/s11172-009-0124-1

M3 - Article

SN - 1066-5285

VL - 58

SP - 968

EP - 970

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 5

ER -

Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

Abstract

Keywords

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