Synthesis of molecular vanadium(III) phosphonates

Sumit Khanra; Marc Kloth; Hassanatu Mansaray; Christopher A. Muryn; Floriana Tuna; E. Carolina Sañudo; Madeleine Helliwell; Eric J L Mclnnes; Richard E P Winpenny; Eric Mcinnes

doi:10.1002/anie.200701115

Synthesis of molecular vanadium(III) phosphonates

Sumit Khanra, Marc Kloth, Hassanatu Mansaray, Christopher A. Muryn, Floriana Tuna, E. Carolina Sañudo, Madeleine Helliwell, Eric J L Mclnnes, Richard E P Winpenny, Eric Mcinnes

Research output: Contribution to journal › Article › peer-review

Abstract

All in the family: Organophosphonate complexes of high-valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium (III)-based phosphonates, including the layered {VIII12(VIVO)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	5568-5571
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	29
DOIs	https://doi.org/10.1002/anie.200701115
Publication status	Published - 2007

Keywords

Magnetic properties
Phosphonate ligands
Solvothermal synthesis
Vanadium
X-ray diffraction

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10.1002/anie.200701115

CCDC 639863: Experimental Crystal Structure Determination
Khanra, S. (Contributor), Kloth, M. (Contributor), Mansaray, H. (Contributor), Muryn, C. A. (Contributor), Tuna, F. (Contributor), Sañudo, E. C. (Contributor), Helliwell, M. (Contributor), Mcinnes, E. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpgtrp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpgtrp&sid=DataCite
Dataset
CCDC 639860: Experimental Crystal Structure Determination
Khanra, S. (Contributor), Kloth, M. (Contributor), Mansaray, H. (Contributor), Muryn, C. A. (Contributor), Tuna, F. (Contributor), Sañudo, E. C. (Contributor), Helliwell, M. (Contributor), Mcinnes, E. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpgtnl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpgtnl&sid=DataCite
Dataset
CCDC 639864: Experimental Crystal Structure Determination
Khanra, S. (Contributor), Kloth, M. (Contributor), Mansaray, H. (Contributor), Muryn, C. A. (Contributor), Tuna, F. (Contributor), Sañudo, E. C. (Contributor), Helliwell, M. (Contributor), Mcinnes, E. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpgtsq, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpgtsq&sid=DataCite
Dataset

Cite this

@article{972e72ca453c487eb1425bf0296b17b5,

title = "Synthesis of molecular vanadium(III) phosphonates",

abstract = "All in the family: Organophosphonate complexes of high-valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium (III)-based phosphonates, including the layered {VIII12(VIVO)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported. (Figure Presented) {\textcopyright} 2007 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Magnetic properties, Phosphonate ligands, Solvothermal synthesis, Vanadium, X-ray diffraction",

author = "Sumit Khanra and Marc Kloth and Hassanatu Mansaray and Muryn, {Christopher A.} and Floriana Tuna and Sa{\~n}udo, {E. Carolina} and Madeleine Helliwell and Mclnnes, {Eric J L} and Winpenny, {Richard E P} and Eric Mcinnes",

year = "2007",

doi = "10.1002/anie.200701115",

language = "English",

volume = "46",

pages = "5568--5571",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

number = "29",

}

TY - JOUR

T1 - Synthesis of molecular vanadium(III) phosphonates

AU - Khanra, Sumit

AU - Kloth, Marc

AU - Mansaray, Hassanatu

AU - Muryn, Christopher A.

AU - Tuna, Floriana

AU - Sañudo, E. Carolina

AU - Helliwell, Madeleine

AU - Mclnnes, Eric J L

AU - Winpenny, Richard E P

AU - Mcinnes, Eric

PY - 2007

Y1 - 2007

N2 - All in the family: Organophosphonate complexes of high-valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium (III)-based phosphonates, including the layered {VIII12(VIVO)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - All in the family: Organophosphonate complexes of high-valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium (III)-based phosphonates, including the layered {VIII12(VIVO)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Magnetic properties

KW - Phosphonate ligands

KW - Solvothermal synthesis

KW - Vanadium

KW - X-ray diffraction

U2 - 10.1002/anie.200701115

DO - 10.1002/anie.200701115

M3 - Article

SN - 1433-7851

VL - 46

SP - 5568

EP - 5571

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Synthesis of molecular vanadium(III) phosphonates

Abstract

Keywords

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Datasets

CCDC 639863: Experimental Crystal Structure Determination

CCDC 639860: Experimental Crystal Structure Determination

CCDC 639864: Experimental Crystal Structure Determination

Cite this