Synthesis of new and unusual metal complexes from the reaction of dihalogen adducts of tertiary phosphines with unactivated metal powders.

Stephen M. Godfrey, Charles A. McAuliffe

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    A review on the synthesis of metal complexes from dihalogen adducts of tertiary phosphines. It also discusses the activation of crude metal powders by reagents of PR3X2. The structural chem. of dihalogen adducts of tertiary phosphines is clearly diverse and is sensitive to the nature of R and X. Also the central atom E can play a crucial role, as can the solvent of prepn.
    Original languageEnglish
    Title of host publicationModern Coordination Chemistry
    Publication statusPublished - 2002

    Keywords

    • Phosphines Role: RCT (Reactant), RACT (Reactant or reagent) (dihalogen adducts; synthesis of new and unusual metal complexes from the reaction of dihalogen adducts of tertiary phosphines with unactivated metal powders); Transition metal complexes Role: SPN (Synthetic preparation), PREP (Preparation) (synthesis of new and unusual metal complexes from the reaction of dihalogen adducts of tertiary phosphines with unactivated metal powders); Halogens Role: RCT (Reactant), RACT (Reactant or reagent) (tertiary phosphine adducts; synthesis of new and unusual metal complexes from the reaction of dihalogen adducts of tertiary phosphines with unactivated metal powders)

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