Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes

Reiner Sebastian Sprick; Mario Hoyos; Oscar Navarro; Michael Lewis Turner

doi:10.1016/j.reactfunctpolym.2012.02.008

Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes

Reiner Sebastian Sprick, Mario Hoyos, Oscar Navarro, Michael Lewis Turner

Research output: Contribution to journal › Article › peer-review

Abstract

The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs. © 2012 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	337-340
Number of pages	3
Journal	Reactive and Functional Polymers
Volume	72
Issue number	5
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2012.02.008
Publication status	Published - May 2012

Keywords

Buchwald-Hartwig amination
N-heterocyclic carbene
Organic field-effect transistor
Poly(triarylamine)
Semiconducting polymer

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10.1016/j.reactfunctpolym.2012.02.008

http://dx.doi.org/10.1016/j.reactfunctpolym.2012.02.008

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title = "Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes",

abstract = "The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs. {\textcopyright} 2012 Elsevier Ltd. All rights reserved.",

keywords = "Buchwald-Hartwig amination, N-heterocyclic carbene, Organic field-effect transistor, Poly(triarylamine), Semiconducting polymer",

author = "Sprick, {Reiner Sebastian} and Mario Hoyos and Oscar Navarro and Turner, {Michael Lewis}",

year = "2012",

month = may,

doi = "10.1016/j.reactfunctpolym.2012.02.008",

language = "English",

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journal = "Reactive and Functional Polymers",

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publisher = "Elsevier BV",

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T1 - Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes

AU - Sprick, Reiner Sebastian

AU - Hoyos, Mario

AU - Navarro, Oscar

AU - Turner, Michael Lewis

PY - 2012/5

Y1 - 2012/5

N2 - The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs. © 2012 Elsevier Ltd. All rights reserved.

AB - The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs. © 2012 Elsevier Ltd. All rights reserved.

KW - Buchwald-Hartwig amination

KW - N-heterocyclic carbene

KW - Organic field-effect transistor

KW - Poly(triarylamine)

KW - Semiconducting polymer

U2 - 10.1016/j.reactfunctpolym.2012.02.008

DO - 10.1016/j.reactfunctpolym.2012.02.008

M3 - Article

SN - 1381-5148

VL - 72

SP - 337

EP - 340

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 5

ER -

Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes

Abstract

Keywords

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