Synthesis, structure and conductivity of BaIn0.8Mn0.2O3 − δ

Chengxu Yang; Ting Shu; Hao Zhang; Dong Ji; Zhiwen Shou; Chaojie Xiong; Sihai Yang; Guobao Li; Fuhui Liao; Jianhua Lin

doi:10.1016/j.ssi.2014.01.032

Synthesis, structure and conductivity of BaIn0.8Mn0.2O3 − δ

Chengxu Yang, Ting Shu, Hao Zhang, Dong Ji, Zhiwen Shou, Chaojie Xiong, Sihai Yang, Guobao Li, Fuhui Liao, Jianhua Lin

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

Green BaIn0.80Mn0.20O2.70 (S1) has been synthesized by solid-state reaction under high temperature, and black BaIn0.80Mn0.20O2.60 (RS1) is obtained by treating S1 under vacuum at 500 °C. They were characterized by powder X-ray and neutron diffraction, selected area electron diffraction, magnetic measurement, and impedance spectrum. S1 and RS1 crystallize in Cmcm (a = 5.9722(3), b = 5.9664(3), c = 8.4511(4) Å) and P21/c (a = 5.9328(7), b = 5.9445(11), c = 16.8154(14) Å, β = 90.02(2)°), respectively. Oxide ion vacancies are confirmed to exist in S1 and RS1 by the neutron diffraction data.

Original language	English
Pages (from-to)	42-52
Number of pages	11
Journal	Solid State Ionics
Volume	257
DOIs	https://doi.org/10.1016/j.ssi.2014.01.032
Publication status	Published - 2014

Keywords

Oxide ion conductivity
Ba2In2O5
BaIn0.8Mn0.2O3 − δ
Structure

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10.1016/j.ssi.2014.01.032

http://www.sciencedirect.com/science/article/pii/S0167273814000496

Cite this

@article{5c61998dd4c1432dbe57300270eedd80,

title = "Synthesis, structure and conductivity of BaIn0.8Mn0.2O3 − δ",

abstract = "Green BaIn0.80Mn0.20O2.70 (S1) has been synthesized by solid-state reaction under high temperature, and black BaIn0.80Mn0.20O2.60 (RS1) is obtained by treating S1 under vacuum at 500 °C. They were characterized by powder X-ray and neutron diffraction, selected area electron diffraction, magnetic measurement, and impedance spectrum. S1 and RS1 crystallize in Cmcm (a = 5.9722(3), b = 5.9664(3), c = 8.4511(4) {\AA}) and P21/c (a = 5.9328(7), b = 5.9445(11), c = 16.8154(14) {\AA}, β = 90.02(2)°), respectively. Oxide ion vacancies are confirmed to exist in S1 and RS1 by the neutron diffraction data.",

keywords = "Oxide ion conductivity, Ba2In2O5, BaIn0.8Mn0.2O3 − δ, Structure",

author = "Chengxu Yang and Ting Shu and Hao Zhang and Dong Ji and Zhiwen Shou and Chaojie Xiong and Sihai Yang and Guobao Li and Fuhui Liao and Jianhua Lin",

year = "2014",

doi = "10.1016/j.ssi.2014.01.032",

language = "English",

volume = "257",

pages = "42--52",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Synthesis, structure and conductivity of BaIn0.8Mn0.2O3 − δ

AU - Yang, Chengxu

AU - Shu, Ting

AU - Zhang, Hao

AU - Ji, Dong

AU - Shou, Zhiwen

AU - Xiong, Chaojie

AU - Yang, Sihai

AU - Li, Guobao

AU - Liao, Fuhui

AU - Lin, Jianhua

PY - 2014

Y1 - 2014

N2 - Green BaIn0.80Mn0.20O2.70 (S1) has been synthesized by solid-state reaction under high temperature, and black BaIn0.80Mn0.20O2.60 (RS1) is obtained by treating S1 under vacuum at 500 °C. They were characterized by powder X-ray and neutron diffraction, selected area electron diffraction, magnetic measurement, and impedance spectrum. S1 and RS1 crystallize in Cmcm (a = 5.9722(3), b = 5.9664(3), c = 8.4511(4) Å) and P21/c (a = 5.9328(7), b = 5.9445(11), c = 16.8154(14) Å, β = 90.02(2)°), respectively. Oxide ion vacancies are confirmed to exist in S1 and RS1 by the neutron diffraction data.

AB - Green BaIn0.80Mn0.20O2.70 (S1) has been synthesized by solid-state reaction under high temperature, and black BaIn0.80Mn0.20O2.60 (RS1) is obtained by treating S1 under vacuum at 500 °C. They were characterized by powder X-ray and neutron diffraction, selected area electron diffraction, magnetic measurement, and impedance spectrum. S1 and RS1 crystallize in Cmcm (a = 5.9722(3), b = 5.9664(3), c = 8.4511(4) Å) and P21/c (a = 5.9328(7), b = 5.9445(11), c = 16.8154(14) Å, β = 90.02(2)°), respectively. Oxide ion vacancies are confirmed to exist in S1 and RS1 by the neutron diffraction data.

KW - Oxide ion conductivity

KW - Ba2In2O5

KW - BaIn0.8Mn0.2O3 − δ

KW - Structure

U2 - 10.1016/j.ssi.2014.01.032

DO - 10.1016/j.ssi.2014.01.032

M3 - Article

SN - 0167-2738

VL - 257

SP - 42

EP - 52

JO - Solid State Ionics

JF - Solid State Ionics

ER -

Synthesis, structure and conductivity of BaIn0.8Mn0.2O3 − δ

Abstract

Keywords

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