Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)

S. Yang; G B Li; S J Tian; F H Liao; J H Lin

doi:10.1002/ejic.200600103

Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)

S. Yang, G B Li, S J Tian, F H Liao, J H Lin

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction Of V2O5 with H(2)C(2)O(4)(.)2H(2)O in the presence of H3BO3 under hydrothermal conditions has afforded V2O2(OH)(2)(C2O4)(H2O)(2) (1), which crystallizes in the triclinic system, space group P (1) over bar with a = 5.2405(10) angstrom, b = 5.7340(11) angstrom, c = 7.1778(14) angstrom, a = 76.44(3)degrees, beta= 69.37(3)degrees, gamma = 75.37 (3)degrees. The vanadium atoms in I form dimers by sharing edges consisting of p-OH groups, and these dimers are connected further by oxalate ligands to form chains. The magnetic susceptibility data of I fit excellently with the Heisenberg dimer model in the temperature interval 2-300 K. Compound 1 is antiferromagnetic with a J value of -29.6 cm(-1). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

Original language	English
Pages (from-to)	2850-2854
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	14
DOIs	https://doi.org/10.1002/ejic.200600103
Publication status	Published - 2006

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10.1002/ejic.200600103

CCDC 294373: Experimental Crystal Structure Determination
Yang, S. (Contributor), Li, G. B. (Contributor), Tian, S. J. (Contributor), Liao, F. H. (Contributor) & Lin, J. H. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2006
DOI: 10.5517/cc9w9xc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9w9xc&sid=DataCite
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@article{26cc6cde05584127ab56fe721b8d5fee,

title = "Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)",

abstract = "The reaction Of V2O5 with H(2)C(2)O(4)(.)2H(2)O in the presence of H3BO3 under hydrothermal conditions has afforded V2O2(OH)(2)(C2O4)(H2O)(2) (1), which crystallizes in the triclinic system, space group P (1) over bar with a = 5.2405(10) angstrom, b = 5.7340(11) angstrom, c = 7.1778(14) angstrom, a = 76.44(3)degrees, beta= 69.37(3)degrees, gamma = 75.37 (3)degrees. The vanadium atoms in I form dimers by sharing edges consisting of p-OH groups, and these dimers are connected further by oxalate ligands to form chains. The magnetic susceptibility data of I fit excellently with the Heisenberg dimer model in the temperature interval 2-300 K. Compound 1 is antiferromagnetic with a J value of -29.6 cm(-1). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).",

author = "S. Yang and Li, {G B} and Tian, {S J} and Liao, {F H} and Lin, {J H}",

note = "Times Cited: 3",

year = "2006",

doi = "10.1002/ejic.200600103",

language = "English",

pages = "2850--2854",

journal = "European Journal of Inorganic Chemistry",

issn = "1099-0682",

publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)

AU - Yang, S.

AU - Li, G B

AU - Tian, S J

AU - Liao, F H

AU - Lin, J H

N1 - Times Cited: 3

PY - 2006

Y1 - 2006

N2 - The reaction Of V2O5 with H(2)C(2)O(4)(.)2H(2)O in the presence of H3BO3 under hydrothermal conditions has afforded V2O2(OH)(2)(C2O4)(H2O)(2) (1), which crystallizes in the triclinic system, space group P (1) over bar with a = 5.2405(10) angstrom, b = 5.7340(11) angstrom, c = 7.1778(14) angstrom, a = 76.44(3)degrees, beta= 69.37(3)degrees, gamma = 75.37 (3)degrees. The vanadium atoms in I form dimers by sharing edges consisting of p-OH groups, and these dimers are connected further by oxalate ligands to form chains. The magnetic susceptibility data of I fit excellently with the Heisenberg dimer model in the temperature interval 2-300 K. Compound 1 is antiferromagnetic with a J value of -29.6 cm(-1). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

AB - The reaction Of V2O5 with H(2)C(2)O(4)(.)2H(2)O in the presence of H3BO3 under hydrothermal conditions has afforded V2O2(OH)(2)(C2O4)(H2O)(2) (1), which crystallizes in the triclinic system, space group P (1) over bar with a = 5.2405(10) angstrom, b = 5.7340(11) angstrom, c = 7.1778(14) angstrom, a = 76.44(3)degrees, beta= 69.37(3)degrees, gamma = 75.37 (3)degrees. The vanadium atoms in I form dimers by sharing edges consisting of p-OH groups, and these dimers are connected further by oxalate ligands to form chains. The magnetic susceptibility data of I fit excellently with the Heisenberg dimer model in the temperature interval 2-300 K. Compound 1 is antiferromagnetic with a J value of -29.6 cm(-1). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

U2 - 10.1002/ejic.200600103

DO - 10.1002/ejic.200600103

M3 - Article

SN - 1099-0682

SP - 2850

EP - 2854

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 14

ER -

Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)

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CCDC 294373: Experimental Crystal Structure Determination

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