Abstract
Ni2(H2O)(en)2(BDC)2 (1) (en = ethylenediamine, BDC = 1,4-benzenedicarboxylate), has been synthesized hydrothermally. 1 Crystallizes in orthorhombic space group Fddd with a = 10.623(2) Å, b = 21.104(4) Å, and c = 42.829(9) Å. 1 is constructed from stacked neutral layers, [Ni2(H2O)(en)2(BDC)2]n. Ni ions in the structure coordinate to four oxygen atoms and two nitrogen atoms to form NiO4N2 octahedra and two NiO4N2 octahedra connect to each other with a common oxygen atom to form a Ni2O7N4 dimer. Magnetic measurement shows that the dominant magnetic exchange interactions of 1 are ferromagnetic in origin. TG–DSC studies show that 1 is stable up to 300 °C.
| Original language | English |
|---|---|
| Pages (from-to) | 184-189 |
| Number of pages | 6 |
| Journal | Journal of Molecular Structure |
| Volume | 1010 |
| DOIs | |
| Publication status | Published - 2012 |
Keywords
- Metal organic framework
- Nickel (II) 1,4-benzenedicarboxylate (H2BDC)
- Hydrothermal synthesis
- Structure
- 2D layer
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CCDC 693705: Experimental Crystal Structure Determination
Hua, W. (Contributor), Fu, Y. (Contributor), Su, J. (Contributor), Yang, S. (Contributor), Li, G. (Contributor), Liao, F. (Contributor) & Lin, J. (Contributor), Cambridge Crystallographic Data Centre, 3 Jul 2008
DOI: 10.5517/ccr8vlf, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccr8vlf&sid=DataCite
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