Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process

Liang Zhao; Zhiqiang Xu; Laurence K Thompson; Sarah L Heath; David O Miller; Masaaki Ohba

Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process

Liang Zhao, Zhiqiang Xu, Laurence K Thompson, Sarah L Heath, David O Miller, Masaaki Ohba

Research output: Contribution to journal › Article › peer-review

Abstract

The nonanuclear copper complex [Cu9(2paop-H)6](NO3)12·9H2O (2paop = I) was prepd. and its crystal structure detd. The complex forms a [3 × 3] square grid of copper atoms with the ligand bonding in a heptadentate manner by five nitrogen atoms and two bridging oxygen atoms. Variable temp. magnetic susceptibility and magnetization data show that the complex displays predominantly ferromagnetic behavior at low temp., but a small intramol. antiferromagnetic exchange component may be present. [on SciFinder(R)]

Original language	English
Pages (from-to)	3114-3117
Number of pages	4
Journal	Angew. Chem., Int. Ed.
Volume	39
Issue number	17
Publication status	Published - 2000

Keywords

copper pyridinedicarboxylic pyridinylmethylhydrazidato prepn structure magnetism
crystal structure copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear
magnetic property copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear

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Zhao, L., Xu, Z., Thompson, L. K., Heath, S. L., Miller, D. O., & Ohba, M. (2000). Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process. Angew. Chem., Int. Ed., 39(17), 3114-3117. http://onlinelibrary.wiley.com/store/10.1002/1521-3773(20000901)39:17%3C3114::AID-ANIE3114%3E3.0.CO;2-Z/asset/3114_ftp.pdf?v=1&t=ih7r2e9e&s=a7c979418cc5f85fe3e563af98d11db4c2612729

@article{23f8901574984a4a85575b3790c43b1d,

title = "Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process",

abstract = "The nonanuclear copper complex [Cu9(2paop-H)6](NO3)12·9H2O (2paop = I) was prepd. and its crystal structure detd. The complex forms a [3 × 3] square grid of copper atoms with the ligand bonding in a heptadentate manner by five nitrogen atoms and two bridging oxygen atoms. Variable temp. magnetic susceptibility and magnetization data show that the complex displays predominantly ferromagnetic behavior at low temp., but a small intramol. antiferromagnetic exchange component may be present. [on SciFinder(R)]",

keywords = "copper pyridinedicarboxylic pyridinylmethylhydrazidato prepn structure magnetism, crystal structure copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear, magnetic property copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear",

author = "Liang Zhao and Zhiqiang Xu and Thompson, {Laurence K} and Heath, {Sarah L} and Miller, {David O} and Masaaki Ohba",

note = "CAPLUS AN 2000:651391(Journal)",

year = "2000",

language = "English",

volume = "39",

pages = "3114--3117",

journal = "Angew. Chem., Int. Ed.",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

number = "17",

}

Zhao, L, Xu, Z, Thompson, LK, Heath, SL, Miller, DO & Ohba, M 2000, 'Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process', Angew. Chem., Int. Ed., vol. 39, no. 17, pp. 3114-3117. <http://onlinelibrary.wiley.com/store/10.1002/1521-3773(20000901)39:17%3C3114::AID-ANIE3114%3E3.0.CO;2-Z/asset/3114_ftp.pdf?v=1&t=ih7r2e9e&s=a7c979418cc5f85fe3e563af98d11db4c2612729>

TY - JOUR

T1 - Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process

AU - Zhao, Liang

AU - Xu, Zhiqiang

AU - Thompson, Laurence K

AU - Heath, Sarah L

AU - Miller, David O

AU - Ohba, Masaaki

N1 - CAPLUS AN 2000:651391(Journal)

PY - 2000

Y1 - 2000

N2 - The nonanuclear copper complex [Cu9(2paop-H)6](NO3)12·9H2O (2paop = I) was prepd. and its crystal structure detd. The complex forms a [3 × 3] square grid of copper atoms with the ligand bonding in a heptadentate manner by five nitrogen atoms and two bridging oxygen atoms. Variable temp. magnetic susceptibility and magnetization data show that the complex displays predominantly ferromagnetic behavior at low temp., but a small intramol. antiferromagnetic exchange component may be present. [on SciFinder(R)]

AB - The nonanuclear copper complex [Cu9(2paop-H)6](NO3)12·9H2O (2paop = I) was prepd. and its crystal structure detd. The complex forms a [3 × 3] square grid of copper atoms with the ligand bonding in a heptadentate manner by five nitrogen atoms and two bridging oxygen atoms. Variable temp. magnetic susceptibility and magnetization data show that the complex displays predominantly ferromagnetic behavior at low temp., but a small intramol. antiferromagnetic exchange component may be present. [on SciFinder(R)]

KW - copper pyridinedicarboxylic pyridinylmethylhydrazidato prepn structure magnetism

KW - crystal structure copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear

KW - magnetic property copper pyridinedicarboxylic pyridinylmethylhydrazidato nonanuclear

M3 - Article

SN - 1433-7851

VL - 39

SP - 3114

EP - 3117

JO - Angew. Chem., Int. Ed.

JF - Angew. Chem., Int. Ed.

IS - 17

ER -

Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 × 3] square grid generated by a strict self-assembly process

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Keywords

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