Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III)

Vitaliy Khutoryanskiy; V. V. Khutoryanskiy; Z. S. Nurkeeva; G. A. Mun; A. D. Sergaziyev; S. Kadlubowski; N. A. Fefelova; T. Baizhumanova; J. M. Rosiak

doi:10.1002/polb.10693

Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III)

Vitaliy Khutoryanskiy, V. V. Khutoryanskiy, Z. S. Nurkeeva, G. A. Mun, A. D. Sergaziyev, S. Kadlubowski, N. A. Fefelova, T. Baizhumanova, J. M. Rosiak

Research output: Contribution to journal › Article › peer-review

Abstract

Water-soluble temperature-responsive polyelectrolytes and hydrogels have been synthesized by γ-radiation copolymerization of [2-(methacryloyloxy)-ethyl]trimethylammonium chloride with N-isopropylacrylamide. Com-plex formation of soluble copolymers with potassium hexacyanoferrates (II, III) was studied in aqueous solutions. It was shown that, depending on the concentration and temperature, the formation of soluble or insoluble polycomplexes is observed. The hydrogels show good ability to absorb potassium hexacyanoferrates (II, III) from aqueous solutions. Sorption ability of hydrogels depends on the content of cationic monomer in copolymer and the nature of coordination ion. © 2003 Wiley Periodicals, Inc.

Original language	English
Pages (from-to)	515-522
Number of pages	7
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	42
Issue number	3
DOIs	https://doi.org/10.1002/polb.10693
Publication status	Published - 1 Feb 2004

Keywords

Cationic polyelectrolytes
Hydrogels
MADQUAT
N-isopropylacrylamide
Phase separation
Polycomplexes
Sorption

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10.1002/polb.10693

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Khutoryanskiy, V., Khutoryanskiy, V. V., Nurkeeva, Z. S., Mun, G. A., Sergaziyev, A. D., Kadlubowski, S., Fefelova, N. A., Baizhumanova, T., & Rosiak, J. M. (2004). Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III). Journal of Polymer Science, Part B: Polymer Physics, 42(3), 515-522. https://doi.org/10.1002/polb.10693

Khutoryanskiy, Vitaliy ; Khutoryanskiy, V. V. ; Nurkeeva, Z. S. et al. / Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III). In: Journal of Polymer Science, Part B: Polymer Physics. 2004 ; Vol. 42, No. 3. pp. 515-522.

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title = "Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III)",

abstract = "Water-soluble temperature-responsive polyelectrolytes and hydrogels have been synthesized by γ-radiation copolymerization of [2-(methacryloyloxy)-ethyl]trimethylammonium chloride with N-isopropylacrylamide. Com-plex formation of soluble copolymers with potassium hexacyanoferrates (II, III) was studied in aqueous solutions. It was shown that, depending on the concentration and temperature, the formation of soluble or insoluble polycomplexes is observed. The hydrogels show good ability to absorb potassium hexacyanoferrates (II, III) from aqueous solutions. Sorption ability of hydrogels depends on the content of cationic monomer in copolymer and the nature of coordination ion. {\textcopyright} 2003 Wiley Periodicals, Inc.",

keywords = "Cationic polyelectrolytes, Hydrogels, MADQUAT, N-isopropylacrylamide, Phase separation, Polycomplexes, Sorption",

author = "Vitaliy Khutoryanskiy and Khutoryanskiy, {V. V.} and Nurkeeva, {Z. S.} and Mun, {G. A.} and Sergaziyev, {A. D.} and S. Kadlubowski and Fefelova, {N. A.} and T. Baizhumanova and Rosiak, {J. M.}",

year = "2004",

month = feb,

day = "1",

doi = "10.1002/polb.10693",

language = "English",

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Khutoryanskiy, V, Khutoryanskiy, VV, Nurkeeva, ZS, Mun, GA, Sergaziyev, AD, Kadlubowski, S, Fefelova, NA, Baizhumanova, T & Rosiak, JM 2004, 'Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III)', Journal of Polymer Science, Part B: Polymer Physics, vol. 42, no. 3, pp. 515-522. https://doi.org/10.1002/polb.10693

Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III). / Khutoryanskiy, Vitaliy; Khutoryanskiy, V. V.; Nurkeeva, Z. S. et al.
In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 42, No. 3, 01.02.2004, p. 515-522.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III)

AU - Khutoryanskiy, Vitaliy

AU - Khutoryanskiy, V. V.

AU - Nurkeeva, Z. S.

AU - Mun, G. A.

AU - Sergaziyev, A. D.

AU - Kadlubowski, S.

AU - Fefelova, N. A.

AU - Baizhumanova, T.

AU - Rosiak, J. M.

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N2 - Water-soluble temperature-responsive polyelectrolytes and hydrogels have been synthesized by γ-radiation copolymerization of [2-(methacryloyloxy)-ethyl]trimethylammonium chloride with N-isopropylacrylamide. Com-plex formation of soluble copolymers with potassium hexacyanoferrates (II, III) was studied in aqueous solutions. It was shown that, depending on the concentration and temperature, the formation of soluble or insoluble polycomplexes is observed. The hydrogels show good ability to absorb potassium hexacyanoferrates (II, III) from aqueous solutions. Sorption ability of hydrogels depends on the content of cationic monomer in copolymer and the nature of coordination ion. © 2003 Wiley Periodicals, Inc.

AB - Water-soluble temperature-responsive polyelectrolytes and hydrogels have been synthesized by γ-radiation copolymerization of [2-(methacryloyloxy)-ethyl]trimethylammonium chloride with N-isopropylacrylamide. Com-plex formation of soluble copolymers with potassium hexacyanoferrates (II, III) was studied in aqueous solutions. It was shown that, depending on the concentration and temperature, the formation of soluble or insoluble polycomplexes is observed. The hydrogels show good ability to absorb potassium hexacyanoferrates (II, III) from aqueous solutions. Sorption ability of hydrogels depends on the content of cationic monomer in copolymer and the nature of coordination ion. © 2003 Wiley Periodicals, Inc.

KW - Cationic polyelectrolytes

KW - Hydrogels

KW - MADQUAT

KW - N-isopropylacrylamide

KW - Phase separation

KW - Polycomplexes

KW - Sorption

U2 - 10.1002/polb.10693

DO - 10.1002/polb.10693

M3 - Article

SN - 0887-6266

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JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

IS - 3

ER -

Khutoryanskiy V, Khutoryanskiy VV, Nurkeeva ZS, Mun GA, Sergaziyev AD, Kadlubowski S et al. Temperature-Responsive Linear Polyelectrolytes and Hydrogels Based on [2-(Methacryloyloxy)ethyl] trimethylammonium chloride and N-isopropylacrylamide and Their Complex Formation with Potassium Hexacyanoferrates (II, III). Journal of Polymer Science, Part B: Polymer Physics. 2004 Feb 1;42(3):515-522. doi: 10.1002/polb.10693