Template assembly of metal aggregates by imino-carboxylate ligands

Martin Schroder; Dan MJ Doble; Colin H Benison; Richard D Kay; Wan-Sheung Li; Martin Schröder; Alexander J Blake; Dieter Fenske; Matthew S Jackson

doi:10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO;2-L

Template assembly of metal aggregates by imino-carboxylate ligands

Martin Schroder, Dan MJ Doble, Colin H Benison, Richard D Kay, Wan-Sheung Li, Martin Schröder, Alexander J Blake, Dieter Fenske, Matthew S Jackson

Research output: Contribution to journal › Article › peer-review

Abstract

Lanthanide, main group, and transition metal ion templates provide different polynuclear cages from [M(L)] (M=Ni, Mn; (L)2−=CH2[CH2N=C(CH3)COO−]2). Templating with lanthanum results in a 12-coordinate LaIII ion encapsulated by six [Ni(L)] units, whereas with sodium four Na+ ions are trapped inside a tricapped trigonal prismatic [{Ni(L)}9] cage. With manganese, an octahedrally coordinated MnII ion is surrounded by six [Mn(L)] fragments in a twisted trigonal-prismatic configuration

Original language	English
Pages (from-to)	1915-1918
Number of pages	4
Journal	Angewandte Chemie (International Edition)
Volume	38
Issue number	13-14
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO;2-L
Publication status	Published - Jul 1999

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title = "Template assembly of metal aggregates by imino-carboxylate ligands",

abstract = "Lanthanide, main group, and transition metal ion templates provide different polynuclear cages from [M(L)] (M=Ni, Mn; (L)2−=CH2[CH2N=C(CH3)COO−]2). Templating with lanthanum results in a 12-coordinate LaIII ion encapsulated by six [Ni(L)] units, whereas with sodium four Na+ ions are trapped inside a tricapped trigonal prismatic [{Ni(L)}9] cage. With manganese, an octahedrally coordinated MnII ion is surrounded by six [Mn(L)] fragments in a twisted trigonal-prismatic configuration",

author = "Martin Schroder and Doble, {Dan MJ} and Benison, {Colin H} and Kay, {Richard D} and Wan-Sheung Li and Martin Schr{\"o}der and Blake, {Alexander J} and Dieter Fenske and Jackson, {Matthew S}",

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T1 - Template assembly of metal aggregates by imino-carboxylate ligands

AU - Schroder, Martin

AU - Doble, Dan MJ

AU - Benison, Colin H

AU - Kay, Richard D

AU - Li, Wan-Sheung

AU - Schröder, Martin

AU - Blake, Alexander J

AU - Fenske, Dieter

AU - Jackson, Matthew S

N1 - cited By 86

PY - 1999/7

Y1 - 1999/7

N2 - Lanthanide, main group, and transition metal ion templates provide different polynuclear cages from [M(L)] (M=Ni, Mn; (L)2−=CH2[CH2N=C(CH3)COO−]2). Templating with lanthanum results in a 12-coordinate LaIII ion encapsulated by six [Ni(L)] units, whereas with sodium four Na+ ions are trapped inside a tricapped trigonal prismatic [{Ni(L)}9] cage. With manganese, an octahedrally coordinated MnII ion is surrounded by six [Mn(L)] fragments in a twisted trigonal-prismatic configuration

AB - Lanthanide, main group, and transition metal ion templates provide different polynuclear cages from [M(L)] (M=Ni, Mn; (L)2−=CH2[CH2N=C(CH3)COO−]2). Templating with lanthanum results in a 12-coordinate LaIII ion encapsulated by six [Ni(L)] units, whereas with sodium four Na+ ions are trapped inside a tricapped trigonal prismatic [{Ni(L)}9] cage. With manganese, an octahedrally coordinated MnII ion is surrounded by six [Mn(L)] fragments in a twisted trigonal-prismatic configuration

U2 - 10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO;2-L

DO - 10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO;2-L

M3 - Article

SN - 1433-7851

VL - 38

SP - 1915

EP - 1918

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 13-14

ER -

Template assembly of metal aggregates by imino-carboxylate ligands

Abstract

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