TY - JOUR
T1 - The application of green solvent in a biorefinery using lignocellulosic biomass as a feedstock
AU - New, Eng Kein
AU - Voon, Khai Shing
AU - Yong, Khai Jie
AU - Procentese, Alessandra
AU - Shak, Katrina Pui Yee
AU - Cheng, Chin Kui
AU - Subramonian, Wennie
AU - Wu, Ta Yeong
N1 - Funding Information:
This review work was supported by Ministry of Higher Education, Malaysia, under the Fundamental Research Grant Scheme (FRGS/1/2019/WAB01/MUSM/02/1). Additionally, the authors would like to thank Monash University Malaysia for providing E.K. New, S.K. Tnah and K.J. Yong with postgraduate scholarships.
Funding Information:
This review work was supported by Ministry of Higher Education, Malaysia , under the Fundamental Research Grant Scheme ( FRGS/1/2019/WAB01/MUSM/02/1 ). Additionally, the authors would like to thank Monash University Malaysia for providing E.K. New, S.K. Tnah and K.J. Yong with postgraduate scholarships.
Publisher Copyright:
© 2021 Elsevier Ltd
PY - 2022/4/1
Y1 - 2022/4/1
N2 - The high dependence on crude oil for energy utilization leads to a necessity of finding alternative sustainable resources. Solvents are often employed in valorizing the biomass into bioproducts and other value-added chemicals during treatment stages. Unfortunately, despite the effectiveness of conventional solvents, hindrances such as expensive solvents, unfavourable environmental ramifications, and complicated downstream separation systems often occur. Therefore, the scientific community has been actively investigating more cost-effective, environmentally friendly alternatives and possess the excellent dissolving capability for biomass processing. Generally, ‘green’ solvents are attractive due to their low toxicity, economic value, and biodegradability. Nonetheless, green solvents are not without disadvantages due to their complicated product recovery, recyclability, and high operational cost. This review summarizes and evaluates the recent contributions, including potential advantages, challenges, and drawbacks of green solvents, namely ionic liquids, deep eutectic solvents, water, biomass-derived solvents and carbon dioxide in transforming the lignocellulosic biomass into high-value products. Moreover, research opportunities for future developments and potential upscale implementation of green solvents are also critically discussed.
AB - The high dependence on crude oil for energy utilization leads to a necessity of finding alternative sustainable resources. Solvents are often employed in valorizing the biomass into bioproducts and other value-added chemicals during treatment stages. Unfortunately, despite the effectiveness of conventional solvents, hindrances such as expensive solvents, unfavourable environmental ramifications, and complicated downstream separation systems often occur. Therefore, the scientific community has been actively investigating more cost-effective, environmentally friendly alternatives and possess the excellent dissolving capability for biomass processing. Generally, ‘green’ solvents are attractive due to their low toxicity, economic value, and biodegradability. Nonetheless, green solvents are not without disadvantages due to their complicated product recovery, recyclability, and high operational cost. This review summarizes and evaluates the recent contributions, including potential advantages, challenges, and drawbacks of green solvents, namely ionic liquids, deep eutectic solvents, water, biomass-derived solvents and carbon dioxide in transforming the lignocellulosic biomass into high-value products. Moreover, research opportunities for future developments and potential upscale implementation of green solvents are also critically discussed.
KW - Biomass valorization
KW - Biomass-derived solvents
KW - Carbon dioxide
KW - Deep eutectic solvents
KW - Ionic liquids
KW - Water
U2 - 10.1016/j.jenvman.2021.114385
DO - 10.1016/j.jenvman.2021.114385
M3 - Review article
SN - 0301-4797
VL - 307
JO - Journal of Environmental Management
JF - Journal of Environmental Management
IS - 114385
M1 - 114385
ER -