The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes

Thomas Storr, Christopher Teskey, Michael Greaney

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    Abstract

    A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper mediated coupling of a benzylic radical is operational.
    Original languageEnglish
    Pages (from-to)18169-18178
    JournalChem.Eur. J.
    Volume22
    Issue number50
    Early online date7 Nov 2016
    DOIs
    Publication statusPublished - 12 Dec 2016

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