The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Adam D. Martin; Timothy Easun; Stephen P. Argent; William Lewis; Alexander J. Blake; Martin Schroder

doi:10.1039/C6CE01965J

The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Adam D. Martin, Timothy Easun, Stephen P. Argent, William Lewis, Alexander J. Blake, Martin Schroder

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Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Original language	English
Pages (from-to)	603-607
Journal	CrystEngComm
Volume	19
Issue number	4
Early online date	16 Nov 2016
DOIs	https://doi.org/10.1039/C6CE01965J
Publication status	Published - 2017

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abstract = "Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.",

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AU - Martin, Adam D.

AU - Easun, Timothy

AU - Argent, Stephen P.

AU - Lewis, William

AU - Blake, Alexander J.

AU - Schroder, Martin

PY - 2017

Y1 - 2017

N2 - Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

AB - Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

UR - https://www.scopus.com/pages/publications/85010078543

U2 - 10.1039/C6CE01965J

DO - 10.1039/C6CE01965J

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JF - CrystEngComm

IS - 4

ER -

The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

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